TY - JOUR
T1 - Electronic structure of fluoropolymers
T2 - theory and ESCA measurements
AU - Pireaux, Jean-Jacques
AU - Riga, Joseph
AU - Caudano, Roland
AU - Verbist, Jacques
AU - André, Jean-Marie
AU - Delhalle, Joseph
AU - DELHALLE, [No Value]
PY - 1974
Y1 - 1974
N2 - Theoretical and experimental results for the band structure of fluoropolymers are presented. Original theoretical results are obtained from the extende Hückel method of the following polymers : (I) polyethylene, (II) polyvinyl fluoride, (III) polydifluoro (1,2) ethylene-cis, (IV) polydifluoro (1,2) ethylene-trans, (V) polyvinylidene fluoride, (VI) polytrifluoroethylene and (VII) polytetrafluoroethylene. Band structures schemes and density of state histograms are calculated. Results are compared with valence band structures as revealed by E.S.C.A. spectroscopy, using a flood gun to neutralize char effects on these compounds. In this work, accent is put on the substituent effect of fluorine. Correlation between theoretical and observed density of
AB - Theoretical and experimental results for the band structure of fluoropolymers are presented. Original theoretical results are obtained from the extende Hückel method of the following polymers : (I) polyethylene, (II) polyvinyl fluoride, (III) polydifluoro (1,2) ethylene-cis, (IV) polydifluoro (1,2) ethylene-trans, (V) polyvinylidene fluoride, (VI) polytrifluoroethylene and (VII) polytetrafluoroethylene. Band structures schemes and density of state histograms are calculated. Results are compared with valence band structures as revealed by E.S.C.A. spectroscopy, using a flood gun to neutralize char effects on these compounds. In this work, accent is put on the substituent effect of fluorine. Correlation between theoretical and observed density of
U2 - 10.1016/0368-2048(74)85035-8
DO - 10.1016/0368-2048(74)85035-8
M3 - Article
SN - 0368-2048
VL - 5
SP - 531
EP - 550
JO - Journal of Electron Spectroscopy and Related Phenomena
JF - Journal of Electron Spectroscopy and Related Phenomena
IS - 1
ER -