TY - JOUR
T1 - Electron-energy-loss spectroscopy of plasmon excitations in concentric-shell fullerenes
AU - Henrard, Luc
AU - Malengreau, Frédéric
AU - Rudolf, Petra
AU - Hevesi, Kadosa
AU - Caudano, Roland
AU - Lambin, Philippe
AU - Cabioc'h, Thierry
N1 - Publication code : **RES. ACAD.
PY - 1999
Y1 - 1999
N2 - We report evidence for surface plasmon excitations in concentric-shell fullerenes. A film of these concentric-shell fullerenes with radii around 5–7 nm was produced by carbon bombardment of a silver polycrystalline target and measured by electron-energy-loss spectroscopy (EELS) in reflection geometry. These data were analyzed with the help of a dielectric theory developed for EELS in transmission geometry. Taking into account the concentric-shell–substrate interaction, the spectral shape can be explained as a combination of contributions from σ−π* interband transitions (around 13.5 eV), from the surface radial (σ−π*) and tangential (σ−σ*) plasmons (around 14.5 eV and 16.7 eV, respectively), and from the volume plasmon (24.5 eV).
AB - We report evidence for surface plasmon excitations in concentric-shell fullerenes. A film of these concentric-shell fullerenes with radii around 5–7 nm was produced by carbon bombardment of a silver polycrystalline target and measured by electron-energy-loss spectroscopy (EELS) in reflection geometry. These data were analyzed with the help of a dielectric theory developed for EELS in transmission geometry. Taking into account the concentric-shell–substrate interaction, the spectral shape can be explained as a combination of contributions from σ−π* interband transitions (around 13.5 eV), from the surface radial (σ−π*) and tangential (σ−σ*) plasmons (around 14.5 eV and 16.7 eV, respectively), and from the volume plasmon (24.5 eV).
U2 - 10.1103/PhysRevB.59.5832
DO - 10.1103/PhysRevB.59.5832
M3 - Article
SN - 1098-0121
VL - 59
SP - 5832
EP - 5836
JO - Physical Review. B, Condensed Matter and Materials Physics
JF - Physical Review. B, Condensed Matter and Materials Physics
IS - 8
ER -