Diode-laser measurements of N2-broadening coefficients in the v2 and v5 bands of 12CH3F

M. Lepère, G. Blanquet, J. Walrand, J.-P. Bouanich

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Résumé

N-broadening coefficients have been measured for 28 lines of CHF in the P, Q, and R branches of v parallel band, and in the P, Q, R, P, Q, and R branches of the v perpendicular band, using a tunable diode-laser spectrometer. The lines with J values ranging from 3 to 27, and K from 0 to 6 (K ≤ J), are located in the spectral range 1416-1553 cm. The collisional widths obtained by fitting Rautian profiles to the measured shape of the lines are slightly larger than those derived from Voigt profiles. A semiclassical calculation of the N-broadening coefficients has provided results that are generally in satisfactory agreement with our experimental data.
langue originaleAnglais
Pages (de - à)345-351
Nombre de pages7
journalJournal of molecular spectroscopy
Volume181
Numéro de publication2
Etat de la publicationPublié - 1 févr. 1997

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