Résumé
A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenylselenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved.
langue originale | Anglais |
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Pages (de - à) | 383-393 |
Nombre de pages | 11 |
journal | Molecules |
Volume | 10 |
Numéro de publication | 2 |
Etat de la publication | Publié - févr. 2005 |