Diastereoselective synthesis of 2-phenylselenenyl-1,3-anti-diols and 2-phenylselenenyl-1,3-anti-azido-alcohols via hydroxy- and azido-selenenylation reactions

Serena Riela, Carmela Aprile, Michelangelo Gruttadauria, Paolo Lo Meo, Renato Noto

Résultats de recherche: Contribution à un journal/une revueArticleRevue par des pairs

Résumé

A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenylselenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved.

langue originaleAnglais
Pages (de - à)383-393
Nombre de pages11
journalMolecules
Volume10
Numéro de publication2
Etat de la publicationPublié - févr. 2005

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