Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

A. Krief; A. Froidbise

doi:10.2174/157019305774322680

Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

A. Krief, A. Froidbise

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Résumé

Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.

langue originale	Anglais
Pages (de - à)	299-312
Nombre de pages	14
journal	Mini-Reviews in Organic Chemistry
Volume	2
Numéro de publication	4
Les DOIs	https://doi.org/10.2174/157019305774322680
Etat de la publication	Publié - 1 oct. 2005

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10.2174/157019305774322680

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title = "Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids",

abstract = "Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.",

author = "A. Krief and A. Froidbise",

year = "2005",

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AU - Froidbise, A.

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N2 - Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.

AB - Detailed review on enantioselective synthesis of methyl (IR)-trans-chrysanthemate and related methyl (IR)-cis-deltamethrinate is presented. These commercially available esters of vinylcyclopropanecarboxylic acids belong to pyrethroids class of insecticides. They are used as single enantiomers for domestic and agricultural purpose. They are almost 3.5 10 more active than DDT and are biodegradable.

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Diastereoselective additions to C,C double bonds applied to the enantioselective synthesis of pyrethroic acids

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