Dehydratation-rehydratation behaviour of layered double hydroxyde: a study by X-Ray diffractometry and MAS NMR spectroscopy

A. Béres; I. Palinko; J.-C. Bertrand; Janos B.Nagy; Imre Kiricsi

doi:10.1016/S0022-2860(96)09558-0

Dehydratation-rehydratation behaviour of layered double hydroxyde: a study by X-Ray diffractometry and MAS NMR spectroscopy

A. Béres, I. Palinko, J.-C. Bertrand, Janos B.Nagy, Imre Kiricsi

Résultats de recherche: Contribution à un journal/une revue › Article

Résumé

MgAl and ZnAl double hydroxides were synthesized and their dehydration-rehydration behaviour was studied by X-ray diffractometry and 27Al magic-angle spinning (MAS) NMR spectroscopy. On dehydration the layered structure collapsed, but treatment in water resulted in partial reconstitution of the original structure. On heat treatment part of the octahedrally coordinated aluminium, typical of layered double hydroxides, became tetrahedrally coordinated. On rehydration some of the tetrahedral aluminium became octahedrally coordinated again.

langue originale	Anglais
Pages (de - à)	13-16
Nombre de pages	4
journal	Journal of molecular structure
Volume	410-411
Les DOIs	https://doi.org/10.1016/S0022-2860(96)09558-0
Etat de la publication	Publié - 1998

Accès au document

10.1016/S0022-2860(96)09558-0

Contient cette citation

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title = "Dehydratation-rehydratation behaviour of layered double hydroxyde: a study by X-Ray diffractometry and MAS NMR spectroscopy",

abstract = "MgAl and ZnAl double hydroxides were synthesized and their dehydration-rehydration behaviour was studied by X-ray diffractometry and 27Al magic-angle spinning (MAS) NMR spectroscopy. On dehydration the layered structure collapsed, but treatment in water resulted in partial reconstitution of the original structure. On heat treatment part of the octahedrally coordinated aluminium, typical of layered double hydroxides, became tetrahedrally coordinated. On rehydration some of the tetrahedral aluminium became octahedrally coordinated again.",

author = "A. B{\'e}res and I. Palinko and J.-C. Bertrand and Janos B.Nagy and Imre Kiricsi",

year = "1998",

doi = "10.1016/S0022-2860(96)09558-0",

language = "English",

volume = "410-411",

pages = "13--16",

journal = "Journal of molecular structure",

issn = "0022-2860",

publisher = "Elsevier",

}

TY - JOUR

T1 - Dehydratation-rehydratation behaviour of layered double hydroxyde

T2 - a study by X-Ray diffractometry and MAS NMR spectroscopy

AU - Béres, A.

AU - Palinko, I.

AU - Bertrand, J.-C.

AU - B.Nagy, Janos

AU - Kiricsi, Imre

PY - 1998

Y1 - 1998

N2 - MgAl and ZnAl double hydroxides were synthesized and their dehydration-rehydration behaviour was studied by X-ray diffractometry and 27Al magic-angle spinning (MAS) NMR spectroscopy. On dehydration the layered structure collapsed, but treatment in water resulted in partial reconstitution of the original structure. On heat treatment part of the octahedrally coordinated aluminium, typical of layered double hydroxides, became tetrahedrally coordinated. On rehydration some of the tetrahedral aluminium became octahedrally coordinated again.

AB - MgAl and ZnAl double hydroxides were synthesized and their dehydration-rehydration behaviour was studied by X-ray diffractometry and 27Al magic-angle spinning (MAS) NMR spectroscopy. On dehydration the layered structure collapsed, but treatment in water resulted in partial reconstitution of the original structure. On heat treatment part of the octahedrally coordinated aluminium, typical of layered double hydroxides, became tetrahedrally coordinated. On rehydration some of the tetrahedral aluminium became octahedrally coordinated again.

U2 - 10.1016/S0022-2860(96)09558-0

DO - 10.1016/S0022-2860(96)09558-0

M3 - Article

SN - 0022-2860

VL - 410-411

SP - 13

EP - 16

JO - Journal of molecular structure

JF - Journal of molecular structure

ER -