Controlled Generation of 9-Boratriptycene by Lewis Adduct Dissociation: Accessing a Non‐Planar Triarylborane

Keyphrases

• Boron 100%
• Dissociation 100%
• Lewis Bases 100%
• Non-planar 100%
• Lewis Acidity 100%
• Lewis Adducts 100%
• Triarylborane 100%
• Controlled Generation 100%
• Structural Properties 50%
• Brønsted Acid 50%
• Aryl 50%
• Quantum Chemical Calculations 50%
• Photophysical Properties 50%
• Spectroscopic Properties 50%
• TETRA 50%
• Phosphine 50%
• Sterically Hindered 50%
• Stereoelectronic Properties 50%
• Reorganization Energy 50%
• Ate Complex 50%
• Triptycene 50%
• Pyramidalization 50%
• Aryl Rings 50%
• Iptycene 50%
• Protodeboronation 50%

INIS

• boron 100%
• acidity 100%
• dissociation 100%
• adducts 100%
• lewis bases 100%
• solutions 50%
• energy 50%
• rings 50%
• reactivity 50%
• phosphines 50%

Chemistry

• Lewis Adduct 100%
• Lewis Base 100%
• Structure 50%
• Quantum Chemical Calculations 50%
• Reorganization Energy 50%