Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds

A. Krief; W. Dumont; M. Clarembeau; E. Badaoui

Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds

A. Krief, W. Dumont, M. Clarembeau, E. Badaoui

Unite de recherche en chimie organique

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Résumé

This paper discloses the chemoselective cleavage of selenoacetals. Informations concerning the intimate mechanism of such process are produced as well as unambiguous experimental results concerning the relative stabilization of a carbanionic center by phenylthio, phenylseleno and methylseleno moieties.

langue originale	Anglais
Pages (de - à)	2023-2030
Nombre de pages	8
journal	Tetrahedron
Volume	45
Numéro de publication	7
Etat de la publication	Publié - 1 janv. 1989

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@article{60a96bbbc017441d954b147fa0c8c238,

title = "Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds",

abstract = "This paper discloses the chemoselective cleavage of selenoacetals. Informations concerning the intimate mechanism of such process are produced as well as unambiguous experimental results concerning the relative stabilization of a carbanionic center by phenylthio, phenylseleno and methylseleno moieties.",

author = "A. Krief and W. Dumont and M. Clarembeau and E. Badaoui",

year = "1989",

month = jan,

day = "1",

language = "English",

volume = "45",

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journal = "Tetrahedron",

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T1 - Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds

AU - Krief, A.

AU - Dumont, W.

AU - Clarembeau, M.

AU - Badaoui, E.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - This paper discloses the chemoselective cleavage of selenoacetals. Informations concerning the intimate mechanism of such process are produced as well as unambiguous experimental results concerning the relative stabilization of a carbanionic center by phenylthio, phenylseleno and methylseleno moieties.

AB - This paper discloses the chemoselective cleavage of selenoacetals. Informations concerning the intimate mechanism of such process are produced as well as unambiguous experimental results concerning the relative stabilization of a carbanionic center by phenylthio, phenylseleno and methylseleno moieties.

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M3 - Article

AN - SCOPUS:0000126914

SN - 0040-4020

VL - 45

SP - 2023

EP - 2030

JO - Tetrahedron

JF - Tetrahedron

IS - 7

ER -

Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds

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