Collisional-broadening coefficients in the ν6 band of 12CH3F perturbed by Ar

M. Lepère, G. Blanquet, J. Walrand, J.-P. Bouanich

Résultats de recherche: Contribution à un journal/une revueArticleRevue par des pairs

Résumé

Ar-broadening coefficients are measured for 29 lines of CHF in the Q and Q branches of the ν band, using a tunable diode-laser spectrometer. The collisional widths obtained by fitting Rautian profiles to the measured shapes of the lines are significantly larger, especially for the overlapping lines at low-J values, than those obtained from Voigt profiles. The broadening coefficients for the lines belonging to the same low-J transitions (J = 7-10) appear to be greater in the Q branch than in the RQ branch. Comparisons have been made with calculated results based on a semiclassical model including adjustable potential parameters,
langue originaleAnglais
Pages (de - à)231-234
Nombre de pages4
journalJournal of molecular spectroscopy
Volume192
Numéro de publication1
Etat de la publicationPublié - 1 janv. 1998

Empreinte digitale

Examiner les sujets de recherche de « Collisional-broadening coefficients in the ν6 band of 12CH3F perturbed by Ar ». Ensemble, ils forment une empreinte digitale unique.

Contient cette citation