Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

A. Krief; E. Badaoui; W. Dumont

doi:10.1016/S0040-4039(00)61373-4

Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

A. Krief, E. Badaoui, W. Dumont

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.

langue originale	Anglais
Pages (de - à)	8517-8520
Nombre de pages	4
journal	Tetrahedron Letters
Volume	34
Numéro de publication	52
Les DOIs	https://doi.org/10.1016/S0040-4039(00)61373-4
Etat de la publication	Publié - 1 janv. 1993

Accès au document

10.1016/S0040-4039(00)61373-4

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title = "Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides",

abstract = "Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.",

author = "A. Krief and E. Badaoui and W. Dumont",

year = "1993",

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doi = "10.1016/S0040-4039(00)61373-4",

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T1 - Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

AU - Krief, A.

AU - Badaoui, E.

AU - Dumont, W.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.

AB - Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.

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U2 - 10.1016/S0040-4039(00)61373-4

DO - 10.1016/S0040-4039(00)61373-4

M3 - Article

AN - SCOPUS:0027756778

SN - 0040-4039

VL - 34

SP - 8517

EP - 8520

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 52

ER -

Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

Résumé

Accès au document

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