Cleavage of the C-Se bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides

A. Krief, E. Badaoui, W. Dumont

Résultats de recherche: Contribution à un journal/une revueArticleRevue par des pairs

Résumé

Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less prone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.
langue originaleAnglais
Pages (de - à)8517-8520
Nombre de pages4
journalTetrahedron Letters
Volume34
Numéro de publication52
Les DOIs
Etat de la publicationPublié - 1 janv. 1993

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