Chiral Resolution of Mandelic Acid through Preferential Cocrystallization with Nefiracetam

Xavier Buol, Camila Caro Garrido, Koen Robeyns, Nikolay Tumanov, Laurent Collard, Johan Wouters, Tom Leyssens

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Résumé

In this paper, we identified a cocrystal conglomerate of mandelic acid using a drug compound as a coformer. We then developed a chiral resolution process based on preferential cocrystallization. Several versions of such a process were explored and optimized, leading to a successful resolution of mandelic acid, evidencing the efficiency of our system. Excellent enantiopurity (98-99%) was obtained with a process that can run for multiple cycles.

langue originaleAnglais
Pages (de - à)7979-7988
Nombre de pages10
journalCrystal Growth and Design
Volume20
Numéro de publication12
Date de mise en ligne précoce9 nov. 2020
Les DOIs
Etat de la publicationPublié - 2 déc. 2020

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