TY - JOUR
T1 - Carbon nanotube formation over supported catalysts
AU - Hernadi, Klara
AU - Piedigrosso, Patricia
AU - Fonseca, Antonio
AU - B.Nagy, Janos
AU - Kiricsi, Imre
PY - 1999
Y1 - 1999
N2 - Catalytic synthesis and characterization of multi-wall fullerene nanotubes are presented. Supported transition metal catalysts were prepared by different methods and were tested in the decomposition of hydrocarbons. Reactions were carried out in a fixed bed flow reactor at 700°C at atmo-spheric pressure. Both activity and selectivity of catalyst samples depended mainly on the following parameters: catalyst support, transition metal, initial reactant, and reaction temperature. The quality of the product was charac-terized by TEM. Although the ends of these catalytically produced carbon nanotubes are often closed by fullerenic half-onions, they can be opened with ease in a relatively gentle liquid-phase oxidation procedure. Neither drastic purification process with HF nor oxidative treatment destroyed the quality of the tubes. IR and XPS investigations confirmed that carbon nano-tubes having inner diameter larger than 1–2 nm show graphitic feature.
AB - Catalytic synthesis and characterization of multi-wall fullerene nanotubes are presented. Supported transition metal catalysts were prepared by different methods and were tested in the decomposition of hydrocarbons. Reactions were carried out in a fixed bed flow reactor at 700°C at atmo-spheric pressure. Both activity and selectivity of catalyst samples depended mainly on the following parameters: catalyst support, transition metal, initial reactant, and reaction temperature. The quality of the product was charac-terized by TEM. Although the ends of these catalytically produced carbon nanotubes are often closed by fullerenic half-onions, they can be opened with ease in a relatively gentle liquid-phase oxidation procedure. Neither drastic purification process with HF nor oxidative treatment destroyed the quality of the tubes. IR and XPS investigations confirmed that carbon nano-tubes having inner diameter larger than 1–2 nm show graphitic feature.
U2 - 10.1080/10587259808045333
DO - 10.1080/10587259808045333
M3 - Article
VL - 310
SP - 179
EP - 184
JO - Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals
JF - Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals
ER -