Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

Guillaume Schweicher; Vincent Lemaur; Claude Niebel; Christian Ruzié; Ying Diao; Osamu Goto; Wen Ya Lee; Yeongin Kim; Jean Baptiste Arlin; Jolanta Karpinska; Alan R. Kennedy; Sean R. Parkin; Yoann Olivier; Stefan C.B. Mannsfeld; Jérôme Cornil; Yves H. Geerts; Zhenan Bao

doi:10.1002/adma.201500322

Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

Guillaume Schweicher, Vincent Lemaur, Claude Niebel, Christian Ruzié, Ying Diao, Osamu Goto, Wen Ya Lee, Yeongin Kim, Jean Baptiste Arlin, Jolanta Karpinska, Alan R. Kennedy, Sean R. Parkin, Yoann Olivier, Stefan C.B. Mannsfeld, Jérôme Cornil, Yves H. Geerts, Zhenan Bao

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm² V^-1 s^-1.

langue originale	Anglais
Pages (de - à)	3066-3072
Nombre de pages	7
journal	Advanced materials
Volume	27
Numéro de publication	19
Les DOIs	https://doi.org/10.1002/adma.201500322
Etat de la publication	Publié - 20 mai 2015
Modification externe	Oui

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10.1002/adma.201500322

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Schweicher, G., Lemaur, V., Niebel, C., Ruzié, C., Diao, Y., Goto, O., Lee, W. Y., Kim, Y., Arlin, J. B., Karpinska, J., Kennedy, A. R., Parkin, S. R., Olivier, Y., Mannsfeld, S. C. B., Cornil, J., Geerts, Y. H., & Bao, Z. (2015). Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order. Advanced materials, 27(19), 3066-3072. https://doi.org/10.1002/adma.201500322

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title = "Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order",

abstract = "A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.",

keywords = "high mobility, organic semiconductor, organic transistor, single-crystal",

author = "Guillaume Schweicher and Vincent Lemaur and Claude Niebel and Christian Ruzi{\'e} and Ying Diao and Osamu Goto and Lee, {Wen Ya} and Yeongin Kim and Arlin, {Jean Baptiste} and Jolanta Karpinska and Kennedy, {Alan R.} and Parkin, {Sean R.} and Yoann Olivier and Mannsfeld, {Stefan C.B.} and J{\'e}r{\^o}me Cornil and Geerts, {Yves H.} and Zhenan Bao",

year = "2015",

month = may,

day = "20",

doi = "10.1002/adma.201500322",

language = "English",

volume = "27",

pages = "3066--3072",

journal = "Advanced materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

number = "19",

}

Schweicher, G, Lemaur, V, Niebel, C, Ruzié, C, Diao, Y, Goto, O, Lee, WY, Kim, Y, Arlin, JB, Karpinska, J, Kennedy, AR, Parkin, SR, Olivier, Y, Mannsfeld, SCB, Cornil, J, Geerts, YH & Bao, Z 2015, 'Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order', Advanced materials, VOL. 27, Numéro 19, p. 3066-3072. https://doi.org/10.1002/adma.201500322

Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order. / Schweicher, Guillaume; Lemaur, Vincent; Niebel, Claude et al.
Dans: Advanced materials, Vol 27, Numéro 19, 20.05.2015, p. 3066-3072.

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

TY - JOUR

T1 - Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes

T2 - Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

AU - Schweicher, Guillaume

AU - Lemaur, Vincent

AU - Niebel, Claude

AU - Ruzié, Christian

AU - Diao, Ying

AU - Goto, Osamu

AU - Lee, Wen Ya

AU - Kim, Yeongin

AU - Arlin, Jean Baptiste

AU - Karpinska, Jolanta

AU - Kennedy, Alan R.

AU - Parkin, Sean R.

AU - Olivier, Yoann

AU - Mannsfeld, Stefan C.B.

AU - Cornil, Jérôme

AU - Geerts, Yves H.

AU - Bao, Zhenan

PY - 2015/5/20

Y1 - 2015/5/20

N2 - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.

AB - A series of bulky end-capped [1]benzothieno[3,2-b]benzothiophenes (BTBTs) are developed in order to tune the packing structure via terminal substitution. A coupled theoretical and experimental study allows us to identify 2,7-di-tert-butylBTBT as a new high-performance organic semiconductor with large and well-balanced transfer integrals, as evidenced by quantum-chemical calculations. Single-crystal field-effect transistors show a remarkable average saturation mobility of 7.1 cm2 V-1 s-1.

KW - high mobility

KW - organic semiconductor

KW - organic transistor

KW - single-crystal

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DO - 10.1002/adma.201500322

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SN - 0935-9648

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EP - 3072

JO - Advanced materials

JF - Advanced materials

IS - 19

ER -

Bulky end-capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching high-mobility organic semiconductors by fine tuning of the crystalline solid-state Order

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