Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

A. Krief; M.J. De Vos; S. De Lombart; J. Bosret; F. Couty

doi:10.1016/S0040-4039(97)01416-0

Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

A. Krief, M.J. De Vos, S. De Lombart, J. Bosret, F. Couty

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

langue originale	Anglais
Pages (de - à)	6295-6298
Nombre de pages	4
journal	Tetrahedron Letters
Volume	38
Numéro de publication	35
Les DOIs	https://doi.org/10.1016/S0040-4039(97)01416-0
Etat de la publication	Publié - 1 sept. 1997

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10.1016/S0040-4039(97)01416-0

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title = "Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one",

abstract = "Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.",

author = "A. Krief and {De Vos}, M.J. and {De Lombart}, S. and J. Bosret and F. Couty",

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AU - De Vos, M.J.

AU - De Lombart, S.

AU - Bosret, J.

AU - Couty, F.

PY - 1997/9/1

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N2 - Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

AB - Organoberyllium compounds, generated by transmetallation from Grignard and organolithium reagents react with 2-cyclohexenone to give predominantly the adducts resulting from conjugated addition. The chemoselectivity of this reaction was found to be highly dependent upon the nature of organic moiety and of the conditions used.

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DO - 10.1016/S0040-4039(97)01416-0

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Beryllium dichloride: Efficient promoter for the addition of organolithiums and organomagnesiums to cyclohexen-2-one

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