TY - JOUR
T1 - Ar- and air-broadening coefficients in the ν3 band of CS2 at room and low temperatures
AU - Misago, F.
AU - Lepère, M.
AU - Bouanich, J.-P.
AU - Blanquet, G.
N1 - Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2008/3/1
Y1 - 2008/3/1
N2 - Using a diode-laser spectrometer, Ar-broadening coefficients for 16 spectral lines in the fundamental ν band of CS have been measured at five temperatures: 298.0, 273.2, 248.2, 223.2 and 198.2 K. These lines with J values ranging from 2 to 64 are located in the spectral range 1519-1547 cm. The broadening coefficients are also calculated from a semiclassical impact model performed by using a simple empirical intermolecular potential. From the theoretical and experimental results obtained at the different temperatures, we have determined the n exponent values governing the temperature dependence of the broadening coefficients. The air-broadening coefficients for four spectral lines in the ν band of CS have also been measured experimentally at the same temperatures. They are compared to the values derived from those obtained previously for the perturbers N, O and also Ar. © 2007 Elsevier Inc. All rights reserved.
AB - Using a diode-laser spectrometer, Ar-broadening coefficients for 16 spectral lines in the fundamental ν band of CS have been measured at five temperatures: 298.0, 273.2, 248.2, 223.2 and 198.2 K. These lines with J values ranging from 2 to 64 are located in the spectral range 1519-1547 cm. The broadening coefficients are also calculated from a semiclassical impact model performed by using a simple empirical intermolecular potential. From the theoretical and experimental results obtained at the different temperatures, we have determined the n exponent values governing the temperature dependence of the broadening coefficients. The air-broadening coefficients for four spectral lines in the ν band of CS have also been measured experimentally at the same temperatures. They are compared to the values derived from those obtained previously for the perturbers N, O and also Ar. © 2007 Elsevier Inc. All rights reserved.
UR - http://www.scopus.com/inward/record.url?scp=38949093174&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2007.10.012
DO - 10.1016/j.jms.2007.10.012
M3 - Article
SN - 1096-083X
VL - 248
SP - 14
EP - 19
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
IS - 1
ER -