Résumé
Methyl trans-chrysanthemate has been prepared in few steps from isopropylidenediphenylsulfurane and methyl (E)-3-(3,3-dimethyloxiran-2-yl)prop-2-enoate. The latter was obtained from methyl 4-oxobutenoate or 3-methylbut-2-en-1-ol. The Sharpless catalytic epoxidation reaction allows an asymmetric version of this transformation.
langue originale | Anglais |
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Pages (de - à) | 2019-2022 |
Nombre de pages | 4 |
journal | Synthesis |
Numéro de publication | 14 |
Etat de la publication | Publié - 2002 |