TY - JOUR
T1 - Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically actIVe MOFs
AU - Mouchaham, Georges
AU - Abeykoon, Brian
AU - Giménez-Marqués, Mónica
AU - Navalon, Sergio
AU - Santiago-Portillo, Andrea
AU - Affram, Maame
AU - Guillou, Nathalie
AU - Martineau, Charlotte
AU - Garcia, Hermenegildo
AU - Fateeva, Alexandra
AU - Devic, Thomas
N1 - Funding Information:
This work was supported by the "cellule Energie" of the CNRS.
Publisher Copyright:
© 2017 The Royal Society of Chemistry.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2017
Y1 - 2017
N2 - The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl)porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(iv) or RE(iii) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.
AB - The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl)porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(iv) or RE(iii) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.
UR - http://www.scopus.com/inward/record.url?scp=85021942060&partnerID=8YFLogxK
U2 - 10.1039/c7cc04215a
DO - 10.1039/c7cc04215a
M3 - Article
C2 - 28643828
AN - SCOPUS:85021942060
SN - 1359-7345
VL - 53
SP - 7661
EP - 7664
JO - Chemical Communications
JF - Chemical Communications
IS - 54
ER -