Résumé
This work is the continuation of our previous experimental and theoretical studies aiming at designing efficient nonlinear optical (NLO) switches derived from the benzazolo-oxazolidine core. Here, we report the synthesis and the characterization of the linear and nonlinear optical properties of benzothiazolo[2,3-b]oxazolidine acidochromes by means of hyper-Rayleigh scattering as well as quantum chemical calculations. It is shown that these new derivatives incorporating a benzothiazole subunit exhibit very high static first hyperpolarizability values in their acido-generated form. On the basis of previously reported NLO responses of indolino- and benzimidazolo-oxazolidines, structure-properties relationships within the benzazolo-oxazolidine series are proposed.
langue originale | Anglais |
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Pages (de - à) | 9795-9802 |
Nombre de pages | 8 |
journal | Journal of physical chemistry B |
Volume | 111 |
Numéro de publication | 33 |
Les DOIs | |
Etat de la publication | Publié - 23 août 2007 |