A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi, Federica Valentini, Francesco Ferlin, Lucia Anna Bivona, Ioannis Anastasiou, Luca Fusaro, Carmela Aprile, Assunta Marrocchi, Luigi Vaccaro

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The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

langue originaleAnglais
Pages (de - à)355-360
Nombre de pages6
journalGreen Chemistry
Numéro de publication2
Les DOIs
étatPublié - 2019

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