Résumé
The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.
langue originale | Anglais |
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Pages (de - à) | 355-360 |
Nombre de pages | 6 |
journal | Green Chemistry |
Volume | 21 |
Numéro de publication | 2 |
Les DOIs | |
Etat de la publication | Publié - 2019 |
Empreinte digitale
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Physico-chimie et caractérisation (PC2)
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