A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi; Federica Valentini; Francesco Ferlin; Lucia Anna Bivona; Ioannis Anastasiou; Luca Fusaro; Carmela Aprile; Assunta Marrocchi; Luigi Vaccaro

doi:10.1039/c8gc03228a

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Hamed Mahmoudi, Federica Valentini, Francesco Ferlin, Lucia Anna Bivona, Ioannis Anastasiou, Luca Fusaro, Carmela Aprile, Assunta Marrocchi, Luigi Vaccaro

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

The [PdCl ₄] ^2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

langue originale	Anglais
Pages (de - à)	355-360
Nombre de pages	6
journal	Green Chemistry
Volume	21
Numéro de publication	2
Les DOIs	https://doi.org/10.1039/c8gc03228a
Etat de la publication	Publié - 2019

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10.1039/c8gc03228a

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2019_BivonaFusaroAprile_article
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@article{f825c6aa65e74c92bc4c91fd9f367ea8,

title = "A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL",

abstract = "The [PdCl 4] 2- palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(ii)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck-Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity. ",

author = "Hamed Mahmoudi and Federica Valentini and Francesco Ferlin and Bivona, {Lucia Anna} and Ioannis Anastasiou and Luca Fusaro and Carmela Aprile and Assunta Marrocchi and Luigi Vaccaro",

note = "Funding Information: F. V., F. F., I. A., A. M., and L. V. gratefully acknowledge the Universit{\`a} degli Studi di Perugia and MIUR for financial support to the project AMIS, through the program “Dipartimenti di Eccellenza – 2018-2022”. The authors acknowledge Dr Pierre Louette for his support in the XPS analysis. This research used the resources of the “Plateforme Technologique Physico-Chemical Characterization” – PC2 located at the University of Namur. Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2019",

doi = "10.1039/c8gc03228a",

language = "English",

volume = "21",

pages = "355--360",

journal = "Green Chemistry",

issn = "1463-9270",

publisher = "Royal Society of Chemistry",

number = "2",

}

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL. / Mahmoudi, Hamed; Valentini, Federica; Ferlin, Francesco et al.
Dans: Green Chemistry, Vol 21, Numéro 2, 2019, p. 355-360.

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

TY - JOUR

T1 - A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

AU - Mahmoudi, Hamed

AU - Valentini, Federica

AU - Ferlin, Francesco

AU - Bivona, Lucia Anna

AU - Anastasiou, Ioannis

AU - Fusaro, Luca

AU - Aprile, Carmela

AU - Marrocchi, Assunta

AU - Vaccaro, Luigi

N1 - Funding Information: F. V., F. F., I. A., A. M., and L. V. gratefully acknowledge the Università degli Studi di Perugia and MIUR for financial support to the project AMIS, through the program “Dipartimenti di Eccellenza – 2018-2022”. The authors acknowledge Dr Pierre Louette for his support in the XPS analysis. This research used the resources of the “Plateforme Technologique Physico-Chemical Characterization” – PC2 located at the University of Namur. Publisher Copyright: © 2019 The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2019

Y1 - 2019

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DO - 10.1039/c8gc03228a

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JO - Green Chemistry

JF - Green Chemistry

IS - 2

ER -

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

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