A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes

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Résumé

A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.
langue originaleAnglais
Numéro d'article2314
Pages (de - à)2314
Nombre de pages11
journalMolecules
Volume24
Numéro de publication12
Les DOIs
étatPublié - 1 janv. 2019

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X-Ray Diffraction
routes
Ligands
solid state
ligands
Coordination Complexes
synthesis
Metal complexes
Reaction products
diffraction
reaction products
Powders
X ray powder diffraction
Organic solvents
Nuclear magnetic resonance spectroscopy
x rays
Magnetic Resonance Spectroscopy
Crystal structure
Single crystals
Derivatives

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title = "A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes",
abstract = "A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.",
keywords = "salophen ligands, metal salophen complexes, mechanochemistry, Metal salophen complexes, Salophen ligands, Mechanochemistry",
author = "Luca Fusaro and Andrea Carletta and Jean Dubois and Nikolay Tumanov and Carmela Aprile and Johan Wouters and {Dalla Cort}, Antonella and Luca Leoni",
year = "2019",
month = "1",
day = "1",
doi = "10.3390/molecules24122314",
language = "English",
volume = "24",
pages = "2314",
journal = "Molecules",
issn = "1431-5165",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "12",

}

A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes. / Fusaro, Luca; Carletta, Andrea; Dubois, Jean; Tumanov, Nikolay; Aprile, Carmela; Wouters, Johan; Dalla Cort, Antonella; Leoni, Luca.

Dans: Molecules, Vol 24, Numéro 12, 2314, 01.01.2019, p. 2314.

Résultats de recherche: Contribution à un journal/une revueArticle

TY - JOUR

T1 - A Simple and Efficient Mechanochemical Route for the Synthesis of Salophen Ligands and of the Corresponding Zn, Ni, and Pd Complexes

AU - Fusaro, Luca

AU - Carletta, Andrea

AU - Dubois, Jean

AU - Tumanov, Nikolay

AU - Aprile, Carmela

AU - Wouters, Johan

AU - Dalla Cort, Antonella

AU - Leoni, Luca

PY - 2019/1/1

Y1 - 2019/1/1

N2 - A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.

AB - A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by anefficient one-pot mechanosynthesis protocol. The reaction products were characterized by means ofcomplementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction,and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSOsolvates are here reported. The described simple and relatively fast (about 1 h for all derivatives)procedure is a good alternative to classical methods performed in organic solvents.

KW - salophen ligands

KW - metal salophen complexes

KW - mechanochemistry

KW - Metal salophen complexes

KW - Salophen ligands

KW - Mechanochemistry

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U2 - 10.3390/molecules24122314

DO - 10.3390/molecules24122314

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VL - 24

SP - 2314

JO - Molecules

JF - Molecules

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