Projets par an
Résumé
The elaboration of multichromophoric system which can undergo a reversible transformation over more than two different states can be easily performed by the covalent assembly of several identical switching subunits around a central node. However, the selective addressability of each of them still represents a challenging task. This study reports on the elaboration of multichromophoric systems incorporating three identical indolino-oxazolidine (BOX) moieties as multimodal addressable units. Depending of the open/closed oxazolidine ring status of each of them, these systems can be interconverted between four different states in stepwise manner by using indifferently acid addition or electrochemical stimulation. More important, we have demonstrated by using a dissymmetric triarylamine node that the classical statistical BOX opening is broken then reaching a regioselective addressability. The switching of the three identical BOX units differentiated by their π conjugated junction to the central core follows a preferential order leading to the preponderant and successive formation of only four forms over the eight theoretically and equally expected. To provide limitations and outlooks for such strategy, their switching capacities have been rationalized by DFT calculations.
langue originale | Anglais |
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Numéro d'article | 110270 |
journal | Dyes and pigments |
Volume | 202 |
Les DOIs | |
Etat de la publication | Publié - juin 2022 |
Empreinte digitale
Examiner les sujets de recherche de « A molecular loaded dice: When the π conjugation breaks the statistical addressability of an octastate multimodal molecular switch ». Ensemble, ils forment une empreinte digitale unique.Projets
- 2 Terminé
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CÉCI – Consortium des Équipements de Calcul Intensif
CHAMPAGNE, B. (Responsable du Projet), Lazzaroni, R. (Responsable du Projet), Geuzaine , C. (Co-investigateur), Chatelain, P. (Co-investigateur) & Knaepen, B. (Co-investigateur)
1/01/18 → 31/12/22
Projet: Recherche
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Moriarty: Multi or individual addressability of multi-responsive topological system
CHAMPAGNE, B. (Responsable du Projet), Sanguinet, L. (Responsable du Projet), Beaujean, P. (Responsable du Projet) & Quertinmont, J. (Responsable du Projet)
1/01/17 → 31/12/18
Projet: Recherche
Équipement
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Plateforme Technologique Calcul Intensif
Champagne, B. (!!Manager)
Plateforme technologique Calcul intensifEquipement/installations: Plateforme technolgique