[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy

Vladislav Yu. Shuvalov, Ilia V. Eltsov, Nikolay A. Tumanov, Elena V. Boldyreva, Andrey A. Nefedov, Galina P. Sagitullina

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Résumé

Metacyclophanes have been developed as non-planar aromatic compounds with unusual physical properties. [6]–[9]Metacyclophanes were synthesized by rearrangement of 3-nitro(perhydrocycloalka)[b]pyridinium salts, and analysis of their spectroscopic data and X-ray diffraction patterns indicates the aromaticity and flexibility of their benzene rings. The effectiveness and simplicity of the synthesis makes it possible to use them as available precursors in the synthesis of retinoids, indolophanes, and carbazolophanes.
langue originaleAnglais
Pages (de - à)5410-5416
Nombre de pages7
journalEuropean Journal of Organic Chemistry
Volume2017
Numéro de publication36
Les DOIs
Etat de la publicationPublié - 2 oct. 2017

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Shuvalov, V. Y., Eltsov, I. V., Tumanov, N. A., Boldyreva, E. V., Nefedov, A. A., & Sagitullina, G. P. (2017). [6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy. European Journal of Organic Chemistry, 2017(36), 5410-5416. https://doi.org/10.1002/ejoc.201700946