ω-Alkenyl-α-methoxy-benzyllithiums: Original synthesis and reactivity

A. Krief; J. Bousbaa

doi:10.1016/S0040-4039(97)01411-1

ω-Alkenyl-α-methoxy-benzyllithiums: Original synthesis and reactivity

A. Krief, J. Bousbaa

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.

langue originale	Anglais
Pages (de - à)	6291-6294
Nombre de pages	4
journal	Tetrahedron Letters
Volume	38
Numéro de publication	35
Les DOIs	https://doi.org/10.1016/S0040-4039(97)01411-1
Etat de la publication	Publié - 1 sept. 1997

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10.1016/S0040-4039(97)01411-1

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title = "ω-Alkenyl-α-methoxy-benzyllithiums: Original synthesis and reactivity",

abstract = "1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.",

author = "A. Krief and J. Bousbaa",

year = "1997",

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day = "1",

doi = "10.1016/S0040-4039(97)01411-1",

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journal = "Tetrahedron Letters",

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T1 - ω-Alkenyl-α-methoxy-benzyllithiums

T2 - Original synthesis and reactivity

AU - Krief, A.

AU - Bousbaa, J.

PY - 1997/9/1

Y1 - 1997/9/1

N2 - 1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.

AB - 1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.

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U2 - 10.1016/S0040-4039(97)01411-1

DO - 10.1016/S0040-4039(97)01411-1

M3 - Article

AN - SCOPUS:0030818654

SN - 0040-4039

VL - 38

SP - 6291

EP - 6294

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

ω-Alkenyl-α-methoxy-benzyllithiums: Original synthesis and reactivity

Résumé

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