TY - JOUR
T1 - XPS study of polymer chain conformation in amorphous and crystalline poly(ethyleneterephthalate) sample
AU - Boulanger, Pierre
AU - Pireaux, Jean-Jacques
AU - Verbist, Jacques
AU - Delhalle, Joseph
PY - 1993
Y1 - 1993
N2 - The chain conformations at the surface of poly(ethylene terephthalate) (PET) with amorphous and crystalline (bioriented film) morphologies are characterized by means of IR-ATR spectroscopy. Experimental XPS valence bands are analysed with the help of theoretically simulated XPS valence band spectra for model molecules of PET chains in different conformations. The differences observed in the experimental spectra of the samples are tentatively interpreted as being of conformational origin.
AB - The chain conformations at the surface of poly(ethylene terephthalate) (PET) with amorphous and crystalline (bioriented film) morphologies are characterized by means of IR-ATR spectroscopy. Experimental XPS valence bands are analysed with the help of theoretically simulated XPS valence band spectra for model molecules of PET chains in different conformations. The differences observed in the experimental spectra of the samples are tentatively interpreted as being of conformational origin.
U2 - 10.1016/0368-2048(93)85014-C
DO - 10.1016/0368-2048(93)85014-C
M3 - Article
SN - 0368-2048
VL - 63
SP - 53
EP - 73
JO - Journal of Electron Spectroscopy and Related Phenomena
JF - Journal of Electron Spectroscopy and Related Phenomena
IS - 1
ER -