Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

A. Cravador; A. Krief

Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

A. Cravador, A. Krief

Research output: Contribution to journal › Article › peer-review

Abstract

Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.

Original language	English
Pages (from-to)	2491-2494
Number of pages	4
Journal	Tetrahedron Letters
Volume	22
Issue number	26
Publication status	Published - 1 Jan 1981

Cite this

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abstract = "Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.",

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AB - Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.

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Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

Abstract

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