Unprecedented copper(I) bifluoride complexes: Synthesis, characterization and reactivity

T. Vergote; F. Nahra; A. Welle; N. Mager; O. Riant; T. Leyssens; M. Luhmer; J. Wouters

doi:10.1002/chem.201102655

Unprecedented copper(I) bifluoride complexes: Synthesis, characterization and reactivity

T. Vergote, F. Nahra, A. Welle, N. Mager, O. Riant, T. Leyssens, M. Luhmer, J. Wouters

Research output: Contribution to journal › Article

Abstract

To be or not to bifluoride: Two synthetic pathways to unprecedented N-heterocyclic carbene copper(I) bifluoride complexes have been developed (see scheme). Catalytic tests demonstrated that copper(I) bifluorides are very efficient catalysts, which do not require any additional activating agent. The first Cu-catalyzed diastereoselective allylation of (R)-N-tert-butanesulfinyl aldimines was also established. The method enables efficient, simple and general synthesis of enantiomerically enriched homoallylic amines at room temperature in high yields.

Original language	English
Pages (from-to)	793-798
Number of pages	6
Journal	Chemistry: A European Journal
Volume	18
Issue number	3
DOIs	https://doi.org/10.1002/chem.201102655
Publication status	Published - 16 Jan 2012

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Datasets

CCDC 849634: Experimental Crystal Structure Determination

Leyssens, T. (Contributor), Luhmer, M. (Contributor), Mager, N. (Contributor), Nahra, F. (Contributor), RIANT, O. (Contributor), Vergote, T. (Contributor), Welle, A. (Contributor) & WOUTERS, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012

DOI: 10.5517/ccxj3k2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxj3k2&sid=DataCite

Dataset

CCDC 849633: Experimental Crystal Structure Determination

Leyssens, T. (Contributor), Luhmer, M. (Contributor), Mager, N. (Contributor), Nahra, F. (Contributor), RIANT, O. (Contributor), Vergote, T. (Contributor), Welle, A. (Contributor) & WOUTERS, J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012

DOI: 10.5517/ccxj3j1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxj3j1&sid=DataCite

Dataset

Cite this

Vergote, T., Nahra, F., Welle, A., Mager, N., Riant, O., Leyssens, T., Luhmer, M., & Wouters, J. (2012). Unprecedented copper(I) bifluoride complexes: Synthesis, characterization and reactivity. Chemistry: A European Journal, 18(3), 793-798. https://doi.org/10.1002/chem.201102655

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