The first synthesis of organic diselenolates: Application to the synthesis of diorganyl diselenides

A. Krief; T. Van Wemmel; M. Redon; W. Dumont; C. Delmotte

doi:10.1002/(SICI)1521-3773(19990802)38:15<2245::AID-ANIE2245>3.0.CO;2-J

The first synthesis of organic diselenolates: Application to the synthesis of diorganyl diselenides

A. Krief, T. Van Wemmel, M. Redon, W. Dumont, C. Delmotte

Research output: Contribution to journal › Article › peer-review

Abstract

The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n- butyldisilenol has also been obtained.

Original language	English
Pages (from-to)	2245-2247
Number of pages	3
Journal	Angewandte Chemie. International edition
Volume	38
Issue number	15
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2245::AID-ANIE2245>3.0.CO;2-J
Publication status	Published - 2 Aug 1999

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10.1002/(SICI)1521-3773(19990802)38:15<2245::AID-ANIE2245>3.0.CO;2-J

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abstract = "The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n- butyldisilenol has also been obtained.",

author = "A. Krief and {Van Wemmel}, T. and M. Redon and W. Dumont and C. Delmotte",

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AU - Redon, M.

AU - Dumont, W.

AU - Delmotte, C.

PY - 1999/8/2

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N2 - The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n- butyldisilenol has also been obtained.

AB - The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n- butyldisilenol has also been obtained.

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ER -

The first synthesis of organic diselenolates: Application to the synthesis of diorganyl diselenides

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