The first synthesis of organic diselenolates: Application to the synthesis of diorganyl diselenides

A. Krief, T. Van Wemmel, M. Redon, W. Dumont, C. Delmotte

Research output: Contribution to journalArticle

Abstract

The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n- butyldisilenol has also been obtained.
Original languageEnglish
Pages (from-to)2245-2247
Number of pages3
JournalAngewandte Chemie. International edition
Volume38
Issue number15
DOIs
Publication statusPublished - 2 Aug 1999

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Selenium
Selenic Acid
Atoms
Carbon
Metals

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The first synthesis of organic diselenolates : Application to the synthesis of diorganyl diselenides. / Krief, A.; Van Wemmel, T.; Redon, M.; Dumont, W.; Delmotte, C.

In: Angewandte Chemie. International edition, Vol. 38, No. 15, 02.08.1999, p. 2245-2247.

Research output: Contribution to journalArticle

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AU - Krief, A.

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AU - Dumont, W.

AU - Delmotte, C.

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