Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation

A. Krief, J. Bousbaa

Research output: Contribution to journalArticle

Abstract

ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.
Original languageEnglish
Pages (from-to)1007-1009
Number of pages3
JournalSynlett
Volume1996
Issue number10
Publication statusPublished - 1 Jan 1996

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Bearings (structural)
Stereochemistry
Derivatives
alkoxyl radical

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title = "Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation",
abstract = "ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.",
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Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation. / Krief, A.; Bousbaa, J.

In: Synlett, Vol. 1996, No. 10, 01.01.1996, p. 1007-1009.

Research output: Contribution to journalArticle

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AB - ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.

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