Synthesis of diselenides and selenides from elemental selenium

A. Krief; M. Derock

doi:10.1016/S0040-4039(02)00277-0

Synthesis of diselenides and selenides from elemental selenium

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Abstract

Sodium hydride is able to reduce elemental selenium to sodium diselenide (NaSe), but not to sodium selenide (NaSe). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).

Original language	English
Pages (from-to)	3083-3086
Number of pages	4
Journal	Tetrahedron Letters
Volume	43
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4039(02)00277-0
Publication status	Published - 15 Apr 2002

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title = "Synthesis of diselenides and selenides from elemental selenium",

abstract = "Sodium hydride is able to reduce elemental selenium to sodium diselenide (NaSe), but not to sodium selenide (NaSe). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).",

author = "A. Krief and M. Derock",

year = "2002",

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T1 - Synthesis of diselenides and selenides from elemental selenium

AU - Krief, A.

AU - Derock, M.

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N2 - Sodium hydride is able to reduce elemental selenium to sodium diselenide (NaSe), but not to sodium selenide (NaSe). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).

AB - Sodium hydride is able to reduce elemental selenium to sodium diselenide (NaSe), but not to sodium selenide (NaSe). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).

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U2 - 10.1016/S0040-4039(02)00277-0

DO - 10.1016/S0040-4039(02)00277-0

M3 - Article

AN - SCOPUS:0037090050

SN - 0040-4039

VL - 43

SP - 3083

EP - 3086

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 16

ER -

Synthesis of diselenides and selenides from elemental selenium

Abstract

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