Synthesis of α-CF3 azanorbornene and azetidines by aza Diels-Alder or iodine-mediated cyclizations: application in ROMP and ligand design.

Gilles Berger, Luca Fusaro, Michel Luhmer, Arie van der Lee, Benoit Crousse, Franck. Meyer

Research output: Contribution to journalArticle

Abstract

We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivs., by aza Diels-Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. [on SciFinder(R)]
Original languageEnglish
Pages (from-to)Ahead of Print
JournalTetrahedron Letters
DOIs
Publication statusPublished - 2014
Externally publishedYes

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