Synthesis of α-CF3 azanorbornene and azetidines by aza Diels-Alder or iodine-mediated cyclizations: application in ROMP and ligand design.

Gilles Berger, Luca Fusaro, Michel Luhmer, Arie van der Lee, Benoit Crousse, Franck. Meyer

Research output: Contribution to journalArticle

Abstract

We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivs., by aza Diels-Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. [on SciFinder(R)]
Original languageEnglish
Pages (from-to)Ahead of Print
JournalTetrahedron Letters
DOIs
Publication statusPublished - 2014
Externally publishedYes

Fingerprint

Azetidines
Fluorocarbon Polymers
Cyclization
Iodine
Substitution reactions
Nitrogen
Ligands
azetidine

Cite this

Berger, Gilles ; Fusaro, Luca ; Luhmer, Michel ; van der Lee, Arie ; Crousse, Benoit ; Meyer, Franck. / Synthesis of α-CF3 azanorbornene and azetidines by aza Diels-Alder or iodine-mediated cyclizations: application in ROMP and ligand design. In: Tetrahedron Letters. 2014 ; pp. Ahead of Print.
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abstract = "We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivs., by aza Diels-Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. [on SciFinder(R)]",
author = "Gilles Berger and Luca Fusaro and Michel Luhmer and {van der Lee}, Arie and Benoit Crousse and Franck. Meyer",
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Synthesis of α-CF3 azanorbornene and azetidines by aza Diels-Alder or iodine-mediated cyclizations: application in ROMP and ligand design. / Berger, Gilles; Fusaro, Luca; Luhmer, Michel; van der Lee, Arie; Crousse, Benoit; Meyer, Franck.

In: Tetrahedron Letters, 2014, p. Ahead of Print.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis of α-CF3 azanorbornene and azetidines by aza Diels-Alder or iodine-mediated cyclizations: application in ROMP and ligand design.

AU - Berger, Gilles

AU - Fusaro, Luca

AU - Luhmer, Michel

AU - van der Lee, Arie

AU - Crousse, Benoit

AU - Meyer, Franck.

N1 - M1 - Copyright (C) 2014 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2014:1664411(Journal)

PY - 2014

Y1 - 2014

N2 - We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivs., by aza Diels-Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. [on SciFinder(R)]

AB - We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivs., by aza Diels-Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. [on SciFinder(R)]

U2 - 10.1016/j.tetlet.2014.09.105

DO - 10.1016/j.tetlet.2014.09.105

M3 - Article

SP - Ahead of Print

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

ER -