Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

Akihito Konishi, Yasukazu Hirao, Masayoshi Nakano, Akihiro Shimizu, Edith Botek, Benoît Champagne, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Kouzou Matsumoto, Hiroyuki Kurata, Takashi Kubo

Research output: Contribution to journalArticle

Abstract

A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

Original languageEnglish
Pages (from-to)11021-11023
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number32
DOIs
Publication statusPublished - 18 Aug 2010

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Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
Ground state
Physical properties
Crystalline materials
Derivatives
Molecules

Cite this

Konishi, Akihito ; Hirao, Yasukazu ; Nakano, Masayoshi ; Shimizu, Akihiro ; Botek, Edith ; Champagne, Benoît ; Shiomi, Daisuke ; Sato, Kazunobu ; Takui, Takeji ; Matsumoto, Kouzou ; Kurata, Hiroyuki ; Kubo, Takashi. / Synthesis and characterization of teranthene : A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures. In: Journal of the American Chemical Society. 2010 ; Vol. 132, No. 32. pp. 11021-11023.
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author = "Akihito Konishi and Yasukazu Hirao and Masayoshi Nakano and Akihiro Shimizu and Edith Botek and Beno{\^i}t Champagne and Daisuke Shiomi and Kazunobu Sato and Takeji Takui and Kouzou Matsumoto and Hiroyuki Kurata and Takashi Kubo",
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Konishi, A, Hirao, Y, Nakano, M, Shimizu, A, Botek, E, Champagne, B, Shiomi, D, Sato, K, Takui, T, Matsumoto, K, Kurata, H & Kubo, T 2010, 'Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures', Journal of the American Chemical Society, vol. 132, no. 32, pp. 11021-11023. https://doi.org/10.1021/ja1049737

Synthesis and characterization of teranthene : A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures. / Konishi, Akihito; Hirao, Yasukazu; Nakano, Masayoshi; Shimizu, Akihiro; Botek, Edith; Champagne, Benoît; Shiomi, Daisuke; Sato, Kazunobu; Takui, Takeji; Matsumoto, Kouzou; Kurata, Hiroyuki; Kubo, Takashi.

In: Journal of the American Chemical Society, Vol. 132, No. 32, 18.08.2010, p. 11021-11023.

Research output: Contribution to journalArticle

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T1 - Synthesis and characterization of teranthene

T2 - A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

AU - Konishi, Akihito

AU - Hirao, Yasukazu

AU - Nakano, Masayoshi

AU - Shimizu, Akihiro

AU - Botek, Edith

AU - Champagne, Benoît

AU - Shiomi, Daisuke

AU - Sato, Kazunobu

AU - Takui, Takeji

AU - Matsumoto, Kouzou

AU - Kurata, Hiroyuki

AU - Kubo, Takashi

PY - 2010/8/18

Y1 - 2010/8/18

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