Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

Akihito Konishi; Yasukazu Hirao; Masayoshi Nakano; Akihiro Shimizu; Edith Botek; Benoît Champagne; Daisuke Shiomi; Kazunobu Sato; Takeji Takui; Kouzou Matsumoto; Hiroyuki Kurata; Takashi Kubo

doi:10.1021/ja1049737

Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

Akihito Konishi, Yasukazu Hirao, Masayoshi Nakano, Akihiro Shimizu, Edith Botek, Benoît Champagne, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Kouzou Matsumoto, Hiroyuki Kurata, Takashi Kubo

Unit of theoretical and structural physico-chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

Original language	English
Pages (from-to)	11021-11023
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	32
DOIs	https://doi.org/10.1021/ja1049737
Publication status	Published - 18 Aug 2010

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10.1021/ja1049737

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Konishi, A., Hirao, Y., Nakano, M., Shimizu, A., Botek, E., Champagne, B., Shiomi, D., Sato, K., Takui, T., Matsumoto, K., Kurata, H., & Kubo, T. (2010). Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures. Journal of the American Chemical Society, 132(32), 11021-11023. https://doi.org/10.1021/ja1049737

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title = "Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekul{\'e} structures",

abstract = "A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.",

author = "Akihito Konishi and Yasukazu Hirao and Masayoshi Nakano and Akihiro Shimizu and Edith Botek and Beno{\^i}t Champagne and Daisuke Shiomi and Kazunobu Sato and Takeji Takui and Kouzou Matsumoto and Hiroyuki Kurata and Takashi Kubo",

year = "2010",

month = aug,

day = "18",

doi = "10.1021/ja1049737",

language = "English",

volume = "132",

pages = "11021--11023",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "32",

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Konishi, A, Hirao, Y, Nakano, M, Shimizu, A, Botek, E, Champagne, B, Shiomi, D, Sato, K, Takui, T, Matsumoto, K, Kurata, H & Kubo, T 2010, 'Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures', Journal of the American Chemical Society, vol. 132, no. 32, pp. 11021-11023. https://doi.org/10.1021/ja1049737

TY - JOUR

T1 - Synthesis and characterization of teranthene

T2 - A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

AU - Konishi, Akihito

AU - Hirao, Yasukazu

AU - Nakano, Masayoshi

AU - Shimizu, Akihiro

AU - Botek, Edith

AU - Champagne, Benoît

AU - Shiomi, Daisuke

AU - Sato, Kazunobu

AU - Takui, Takeji

AU - Matsumoto, Kouzou

AU - Kurata, Hiroyuki

AU - Kubo, Takashi

PY - 2010/8/18

Y1 - 2010/8/18

N2 - A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

AB - A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

UR - http://www.scopus.com/inward/record.url?scp=77955587750&partnerID=8YFLogxK

U2 - 10.1021/ja1049737

DO - 10.1021/ja1049737

M3 - Article

AN - SCOPUS:77955587750

SN - 0002-7863

VL - 132

SP - 11021

EP - 11023

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 32

ER -

Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

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CCDC 793359: Experimental Crystal Structure Determination

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Synthesis and characterization of teranthene: A singlet biradical polycyclic aromatic hydrocarbon having kekulé structures

Abstract

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Datasets

CCDC 793359: Experimental Crystal Structure Determination

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