Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)

Bastien Barthélémy; Simon Maheux; Sébastien Devillers; Frédéric Kanoufi; Catherine Combellas; Joseph Delhalle; Zineb Mekhalif

doi:10.1021/am500725d

Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)

Bastien Barthélémy, Simon Maheux, Sébastien Devillers, Frédéric Kanoufi, Catherine Combellas, Joseph Delhalle, Zineb Mekhalif

Research output: Contribution to journal › Article › peer-review

Abstract

Phynox is of high interest for biomedical applications due to its biocompatibility and corrosion resistance. However, some Phynox applications require specific surface properties. These can be imparted with suitable surface functionalizations of its oxide layer. The present work investigates the surface-initiated atom transfer radical polymerization (ATRP) of 2-methacryloyoxyethyl phosphorylcholine (MPC), 2-hydroxyethyl methacrylate (HEMA), and ATRP copolymerization of (HEMA-co-MPC) (block and statistic copolymerization with different molar ratios) on grafted Phynox substrates modified with 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) as initiator. It is found that ATRP (co)polymerization of these monomers is feasible and forms hydrophilic layers, while improving the corrosion resistance of the system.

Original language	English
Pages (from-to)	10060-10071
Number of pages	12
Journal	ACS Applied Materials & Interfaces
Volume	6
Issue number	13
DOIs	https://doi.org/10.1021/am500725d
Publication status	Published - 9 Jul 2014

Keywords

11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid
2-hydroxyethyl methacrylate
2-methacryloyloxyethyl phosphorylcholine
Phynox
surface modification
surface-initiated ATRP

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Synthesis, Irradiation and Analysis of Materials (SIAM)
Louette, P. (Manager), Colaux, J. (Manager), Felten, A. (Manager), Tabarrant, T. (Operator), COME, F. (Operator) & Debarsy, P.-L. (Manager)
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Barthélémy, B., Maheux, S., Devillers, S., Kanoufi, F., Combellas, C., Delhalle, J., & Mekhalif, Z. (2014). Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA). ACS Applied Materials & Interfaces, 6(13), 10060-10071. https://doi.org/10.1021/am500725d

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title = "Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)",

abstract = "Phynox is of high interest for biomedical applications due to its biocompatibility and corrosion resistance. However, some Phynox applications require specific surface properties. These can be imparted with suitable surface functionalizations of its oxide layer. The present work investigates the surface-initiated atom transfer radical polymerization (ATRP) of 2-methacryloyoxyethyl phosphorylcholine (MPC), 2-hydroxyethyl methacrylate (HEMA), and ATRP copolymerization of (HEMA-co-MPC) (block and statistic copolymerization with different molar ratios) on grafted Phynox substrates modified with 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) as initiator. It is found that ATRP (co)polymerization of these monomers is feasible and forms hydrophilic layers, while improving the corrosion resistance of the system.",

keywords = "11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid, 2-hydroxyethyl methacrylate, 2-methacryloyloxyethyl phosphorylcholine, Phynox, surface modification, surface-initiated ATRP",

author = "Bastien Barth{\'e}l{\'e}my and Simon Maheux and S{\'e}bastien Devillers and Fr{\'e}d{\'e}ric Kanoufi and Catherine Combellas and Joseph Delhalle and Zineb Mekhalif",

year = "2014",

month = jul,

day = "9",

doi = "10.1021/am500725d",

language = "English",

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Barthélémy, B, Maheux, S, Devillers, S, Kanoufi, F, Combellas, C, Delhalle, J & Mekhalif, Z 2014, 'Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)', ACS Applied Materials & Interfaces, vol. 6, no. 13, pp. 10060-10071. https://doi.org/10.1021/am500725d

Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA). / Barthélémy, Bastien; Maheux, Simon; Devillers, Sébastien et al.
In: ACS Applied Materials & Interfaces, Vol. 6, No. 13, 09.07.2014, p. 10060-10071.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)

AU - Barthélémy, Bastien

AU - Maheux, Simon

AU - Devillers, Sébastien

AU - Kanoufi, Frédéric

AU - Combellas, Catherine

AU - Delhalle, Joseph

AU - Mekhalif, Zineb

PY - 2014/7/9

Y1 - 2014/7/9

N2 - Phynox is of high interest for biomedical applications due to its biocompatibility and corrosion resistance. However, some Phynox applications require specific surface properties. These can be imparted with suitable surface functionalizations of its oxide layer. The present work investigates the surface-initiated atom transfer radical polymerization (ATRP) of 2-methacryloyoxyethyl phosphorylcholine (MPC), 2-hydroxyethyl methacrylate (HEMA), and ATRP copolymerization of (HEMA-co-MPC) (block and statistic copolymerization with different molar ratios) on grafted Phynox substrates modified with 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) as initiator. It is found that ATRP (co)polymerization of these monomers is feasible and forms hydrophilic layers, while improving the corrosion resistance of the system.

AB - Phynox is of high interest for biomedical applications due to its biocompatibility and corrosion resistance. However, some Phynox applications require specific surface properties. These can be imparted with suitable surface functionalizations of its oxide layer. The present work investigates the surface-initiated atom transfer radical polymerization (ATRP) of 2-methacryloyoxyethyl phosphorylcholine (MPC), 2-hydroxyethyl methacrylate (HEMA), and ATRP copolymerization of (HEMA-co-MPC) (block and statistic copolymerization with different molar ratios) on grafted Phynox substrates modified with 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) as initiator. It is found that ATRP (co)polymerization of these monomers is feasible and forms hydrophilic layers, while improving the corrosion resistance of the system.

KW - 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid

KW - 2-hydroxyethyl methacrylate

KW - 2-methacryloyloxyethyl phosphorylcholine

KW - Phynox

KW - surface modification

KW - surface-initiated ATRP

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U2 - 10.1021/am500725d

DO - 10.1021/am500725d

M3 - Article

AN - SCOPUS:84904097600

SN - 1944-8244

VL - 6

SP - 10060

EP - 10071

JO - ACS Applied Materials & Interfaces

JF - ACS Applied Materials & Interfaces

IS - 13

ER -

Barthélémy B, Maheux S, Devillers S, Kanoufi F, Combellas C, Delhalle J et al. Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA). ACS Applied Materials & Interfaces. 2014 Jul 9;6(13):10060-10071. doi: 10.1021/am500725d

Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)

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Keywords

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