29Si nuclear magnetic resonance of poly(methylphenyl)sila

A. F. De Mahieu, J. DEVAUX, C. Dereppe, G. Baudoux, Joseph Delhalle

Research output: Contribution to journalArticle


A Cl-terminated poly(methylphenyl)silane is synthesized and analyzed by 29Si-NMR spectroscopy. Assignments are proposed for the different peaks observed. A modification of the chemical shifts of the peaks relative to the main chain atoms is observed upon heating. From these experimental results and computational calculations on model compounds, the assignments of the three main peaks to configurationally different Si atoms are confirmed.
Original languageEnglish
Pages (from-to)763-769
Number of pages7
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Issue number5
Publication statusPublished - 1996


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