TY - JOUR
T1 - Structural and electronic properties of coiled and curled carbon nanotubes having a large number of pentagon--heptagon pairs
AU - Lambin, Philippe
AU - Márk, Geza
AU - Biró, Laszlo
PY - 2003
Y1 - 2003
N2 - A family of Haeckelite nanotubes is generated by rolling up a two-dimensional threefold coordinated carbon network composed of pentagon-heptagon pairs and hexagons in proportion 2:3. The corresponding two-dimensional network is highly strained due to the presence of adjacent pentagons and heptagons. When the sheet is folded into a cylinder, part of the strain is released by having the pentagons protrude outward, and sometimes inward the tube. Due to that property, a large variety of structures can be generated such as coiled, screwlike, curled, and pearl-necklace-like nanotubes. All the Haeckelite nanotubes obtained in this work are semiconductors, some having a small band gap. Scanning-tunneling microscopy images, computed for a few Haeckelite nanotubes, show salient topographic protrusions at the location of the pentagon pairs.
AB - A family of Haeckelite nanotubes is generated by rolling up a two-dimensional threefold coordinated carbon network composed of pentagon-heptagon pairs and hexagons in proportion 2:3. The corresponding two-dimensional network is highly strained due to the presence of adjacent pentagons and heptagons. When the sheet is folded into a cylinder, part of the strain is released by having the pentagons protrude outward, and sometimes inward the tube. Due to that property, a large variety of structures can be generated such as coiled, screwlike, curled, and pearl-necklace-like nanotubes. All the Haeckelite nanotubes obtained in this work are semiconductors, some having a small band gap. Scanning-tunneling microscopy images, computed for a few Haeckelite nanotubes, show salient topographic protrusions at the location of the pentagon pairs.
U2 - 10.1103/PhysRevB.67.205413
DO - 10.1103/PhysRevB.67.205413
M3 - Article
SN - 1098-0121
VL - 67
SP - 205413-1-9
JO - Physical Review. B, Condensed Matter and Materials Physics
JF - Physical Review. B, Condensed Matter and Materials Physics
IS - 20
ER -