Structural and electrochemical characterization of fullerene-based surfaces of C60 mono- or bis-adducts grafted onto self-assembled monolayers

Francesca Cecchet; Stefania Rapino; Massimo Margotti; Tatiana Da Ros; Maurizio Prato; Francesco Paolucci; Petra Rudolf

doi:https://doi.org/10.1016/j.carbon.2006.05.024

Structural and electrochemical characterization of fullerene-based surfaces of C60 mono- or bis-adducts grafted onto self-assembled monolayers

Francesca Cecchet, Stefania Rapino, Massimo Margotti, Tatiana Da Ros, Maurizio Prato, Francesco Paolucci, Petra Rudolf

Namur Research Institute for Life Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Single layers of C60 mono- and bis-adducts have been obtained by functionalizing an acid-terminated self-assembled monolayer (SAM) of thiols on gold. X-ray photoelectron spectroscopy demonstrated the grafting onto the SAM by covalent bonding, via the formation of an amide bond, while cyclic voltammetry and electrochemical impedance spectroscopy provided information on the redox properties of the C60-films, as well as on structural characteristics.

Original language	English
Pages (from-to)	3014-3021
Number of pages	8
Journal	Carbon
Volume	44
Issue number	14
DOIs	https://doi.org/10.1016/j.carbon.2006.05.024
Publication status	Published - Nov 2006

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title = "Structural and electrochemical characterization of fullerene-based surfaces of C60 mono- or bis-adducts grafted onto self-assembled monolayers",

abstract = "Single layers of C60 mono- and bis-adducts have been obtained by functionalizing an acid-terminated self-assembled monolayer (SAM) of thiols on gold. X-ray photoelectron spectroscopy demonstrated the grafting onto the SAM by covalent bonding, via the formation of an amide bond, while cyclic voltammetry and electrochemical impedance spectroscopy provided information on the redox properties of the C60-films, as well as on structural characteristics.",

author = "Francesca Cecchet and Stefania Rapino and Massimo Margotti and {Da Ros}, Tatiana and Maurizio Prato and Francesco Paolucci and Petra Rudolf",

year = "2006",

month = nov,

doi = "https://doi.org/10.1016/j.carbon.2006.05.024",

language = "English",

volume = "44",

pages = "3014--3021",

journal = "Carbon",

publisher = "Elsevier",

number = "14",

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TY - JOUR

T1 - Structural and electrochemical characterization of fullerene-based surfaces of C60 mono- or bis-adducts grafted onto self-assembled monolayers

AU - Cecchet, Francesca

AU - Rapino, Stefania

AU - Margotti, Massimo

AU - Da Ros, Tatiana

AU - Prato, Maurizio

AU - Paolucci, Francesco

AU - Rudolf, Petra

PY - 2006/11

Y1 - 2006/11

N2 - Single layers of C60 mono- and bis-adducts have been obtained by functionalizing an acid-terminated self-assembled monolayer (SAM) of thiols on gold. X-ray photoelectron spectroscopy demonstrated the grafting onto the SAM by covalent bonding, via the formation of an amide bond, while cyclic voltammetry and electrochemical impedance spectroscopy provided information on the redox properties of the C60-films, as well as on structural characteristics.

AB - Single layers of C60 mono- and bis-adducts have been obtained by functionalizing an acid-terminated self-assembled monolayer (SAM) of thiols on gold. X-ray photoelectron spectroscopy demonstrated the grafting onto the SAM by covalent bonding, via the formation of an amide bond, while cyclic voltammetry and electrochemical impedance spectroscopy provided information on the redox properties of the C60-films, as well as on structural characteristics.

U2 - https://doi.org/10.1016/j.carbon.2006.05.024

DO - https://doi.org/10.1016/j.carbon.2006.05.024

M3 - Article

VL - 44

SP - 3014

EP - 3021

JO - Carbon

JF - Carbon

IS - 14

ER -

Structural and electrochemical characterization of fullerene-based surfaces of C60 mono- or bis-adducts grafted onto self-assembled monolayers

Abstract

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