Abstract
We present a joint experimental and theoretical study of the structural and charge-transport properties of a liquid-crystalline α,ω- disubstituted oligothiophene derivative for application in organic field-effect transistors. The structural properties of the crystalline and smectic phases are investigated by atomic force microscopy, X-ray reflectometry, and X-ray diffraction. To complement these data, molecular mechanics calculations together with the simulation of X-ray diffraction spectra were performed to determine the relative positions of the molecules in the unit cell. The electrical characteristics of field-effect transistors based on the oligothiophene derivative were measured and compared in the crystalline and smectic phases. Although the silanation of the SiO2 gate dielectric promoted a marked improvement in the charge-carrier mobilities in the crystalline phase, the expected suppression of grain boundaries in the liquid-crystalline phase was not unambiguously evidenced. The experimental results were further complemented by a detailed theoretical analysis of the electronic couplings governing the charge-transport properties on the molecular scale.
Original language | English |
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Pages (from-to) | 4617-4627 |
Number of pages | 11 |
Journal | Journal of Physical Chemistry C: Nanomaterials and interfaces |
Volume | 114 |
Issue number | 10 |
DOIs | |
Publication status | Published - 18 Mar 2010 |
Externally published | Yes |