Abstract
This paper presents a holographic study of the phase transition that occurs in a nonequilibrium system. The chosen model is a unique Briggs-Rauscher oscillatory reaction that, first, follows a deterministic pattern (namely, an oscillatory behavior) and, later, exhibits a phase transition occurring randomly and without any known link with the previous deterministic state. The presented research opens up a new way to reveal complex chemical phenomena and dynamics in situ, without disturbing significantly the nonequilibrium system and its pathways. Simultaneously, it unfolds a new route for applications of interferometric methods in different areas of materials science. Under the applied conditions, we show that the holographic method is more sensitive to the phase transition dynamics than the commonly used potentiometric method.
| Original language | English |
|---|---|
| Pages (from-to) | 10821-10825 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry C: Nanomaterials and interfaces |
| Volume | 127 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 8 Jun 2023 |
Funding
M.S.P., D.Z\u030C.G., D.V., and B.K. acknowledge support of the project Biological and bioinspired structures for multispectral surveillance, funded by NATO SPS (NATO Science for Peace and Security) 2019\u20132022. B.K., D.V., B.B., D.Z\u030C.G., and M.S.-P. acknowledge funding provided by the Institute of Physics Belgrade, through the institutional funding by the Ministry of Education, Science, and Technological Development of the Republic of Serbia. Y.C. is a research associate of the Fund for Scientific Research F.R.S.-FNRS. Additionally, B.K. acknowledges support from F.R.S.-FNRS. M.C.P. acknowledges support from the Ministry of Education, Science and Technological Development of the Republic of Serbia, Contract number 451-03-9/2021-14/200026. S.R.M. was supported by a BEWARE Fellowship (Convention no. 2110034) of the Walloon Region (Marie Sk\u0142odowska-Curie Actions of the European Union - COFUND - contract 847587), as a postdoctoral researcher. T.V. acknowledges financial support from the Hercules Foundation. D.V., M.S.P., D.Z\u030C.G., M.P., B.B., and B.K. acknowledge the support of the Office of Naval Research Global through the Research Grant N62902-22-1-2024. M.S.P., D.Z\u030C.G., D.V., and B.K. acknowledge support of the project Biological and bioinspired structures for multispectral surveillance, funded by NATO SPS (NATO Science for Peace and Security) 2019-2022. B.K., D.V., B.B., D.Z\u030C.G., and M.S.-P. acknowledge funding provided by the Institute of Physics Belgrade, through the institutional funding by the Ministry of Education, Science, and Technological Development of the Republic of Serbia. Y.C. is a research associate of the Fund for Scientific Research F.R.S.-FNRS. Additionally, B.K. acknowledges support from F.R.S.-FNRS. M.C.P. acknowledges support from the Ministry of Education, Science and Technological Development of the Republic of Serbia, Contract number 451-03-9/2021-14/200026. S.R.M. was supported by a BEWARE Fellowship (Convention no. 2110034) of the Walloon Region (Marie Sk\u0142odowska-Curie Actions of the European Union - COFUND - contract 847587), as a postdoctoral researcher. T.V. acknowledges financial support from the Hercules Foundation. D.V., M.S.P., D.Z\u030C.G., M.P., B.B., and B.K. acknowledge the support of the Office of Naval Research Global through the Research Grant N62902-22-1-2024.
| Funders | Funder number |
|---|---|
| Institute of Physics Belgrade | |
| Waalse Gewest | |
| Hercules Foundation | |
| Marie Skłodowska-Curie Actions of the European Union | |
| Fonds De La Recherche Scientifique - FNRS | |
| NATO SPS | |
| NATO Science for Peace and Security | 2019-2022 |
| Office of Naval Research Global | N62902-22-1-2024 |
| Not added | 451-03-9/2021-14/200026, 2110034, 200024 |
| Horizon 2020 Framework Programme | 847587 |