Spontaneous Tl(i)-to-Tl(iii) oxidation in dynamic heterobimetallic Hg(ii)/Tl(i) porphyrin complexes

Victoria Ndoyom, Luca Fusaro, Thierry Roisnel, Stéphane Le Gac, Bernard Boitrel

Research output: Contribution to journalArticlepeer-review

Abstract

Strapped heterobimetallic Hg(ii)/Tl(i) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(i)-to-Tl(iii) oxidation leading to a mono-Tl(iii) complex and a mixed valence Tl(i)/Tl(iii) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.

Original languageEnglish
Pages (from-to)517-520
Number of pages4
JournalChemical Communications
Volume52
Issue number3
DOIs
Publication statusPublished - 30 Oct 2015

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