Spectral intensities in the ν1 band of carbonyl sulfide and its isotopic species

G. Blanquet, J. Walrand, I. Hilgers, D. Lambot

    Research output: Contribution to journalArticlepeer-review

    Abstract

    A tunable diode laser was used to perform measurements of absolute lines intensities in the ν fundamental of carbonyl sulfide. Spectra have also been recorded for the following isotopic species: OCS, OCS and OCS. The vibrational band strength S was calculated at 298 K. The absolute intensity for 100% of OCS species is found to be S = 29.69 ± 0.15 cm atm with the uncertainty covering three times the standard deviation. We have tried to determine the α-coefficient involved in the Hermann-Wallis factor F = (1 + αm + ⋯) and the value is found to be negligible (-5 ± 8) × 10. The S value obtained for the other isotopic species is very close to the normal one.
    Original languageEnglish
    Pages (from-to)295-300
    Number of pages6
    JournalJournal of molecular spectroscopy
    Volume140
    Issue number2
    Publication statusPublished - 1 Apr 1990

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