Simultaneous photocatalytic H2 generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs3Bi2Br9

Chunhua Wang; Bo Weng; Yuhe Liao; Biao Liu; Masoumeh Keshavarz; Yang Ding; Haowei Huang; Davy Verhaeghe; Julian A. Steele; Wenhui Feng; Bao Lian Su; Johan Hofkens; Maarten B.J. Roeffaers

doi:10.1039/d2cc02453e

Simultaneous photocatalytic H₂ generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs₃Bi₂Br₉

Chunhua Wang
, Bo Weng
, Yuhe Liao
, Biao Liu
, Masoumeh Keshavarz
, Yang Ding
, Haowei Huang
, Davy Verhaeghe
, Julian A. Steele
, Wenhui Feng
, Bao Lian Su
, Johan Hofkens
, Maarten B.J. Roeffaers

University of Namur

Research output: Contribution to journal › Article › peer-review

Abstract

Cs₃Bi₂Br₉ decorated with crystalline-amorphous Pd nanocubes as cocatalysts is reported to photocatalytically coproduce ca. 1400 μmol h⁻¹ g⁻¹ of H₂ and benzaldehyde from the selective benzyl alcohol oxidation. This route offers an alternative for photocatalytic H₂ generation using metal halide perovskites under mild conditions.

Original language	English
Pages (from-to)	10691-10694
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	76
DOIs	https://doi.org/10.1039/d2cc02453e
Publication status	Published - 25 Aug 2022

Funding

Funders	Funder number
Horizon 2020 Framework Programme	891276

Access to Document

10.1039/d2cc02453e

Cite this

Wang, C., Weng, B., Liao, Y., Liu, B., Keshavarz, M., Ding, Y., Huang, H., Verhaeghe, D., Steele, J. A., Feng, W., Su, B. L., Hofkens, J., & Roeffaers, M. B. J. (2022). Simultaneous photocatalytic H₂ generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs₃Bi₂Br₉. Chemical Communications, 58(76), 10691-10694. https://doi.org/10.1039/d2cc02453e

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title = "Simultaneous photocatalytic H2 generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs3Bi2Br9",

abstract = "Cs3Bi2Br9 decorated with crystalline-amorphous Pd nanocubes as cocatalysts is reported to photocatalytically coproduce ca. 1400 μmol h−1 g−1 of H2 and benzaldehyde from the selective benzyl alcohol oxidation. This route offers an alternative for photocatalytic H2 generation using metal halide perovskites under mild conditions.",

author = "Chunhua Wang and Bo Weng and Yuhe Liao and Biao Liu and Masoumeh Keshavarz and Yang Ding and Haowei Huang and Davy Verhaeghe and Steele, \{Julian A.\} and Wenhui Feng and Su, \{Bao Lian\} and Johan Hofkens and Roeffaers, \{Maarten B.J.\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = aug,

day = "25",

doi = "10.1039/d2cc02453e",

language = "English",

volume = "58",

pages = "10691--10694",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "76",

}

TY - JOUR

T1 - Simultaneous photocatalytic H2 generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs3Bi2Br9

AU - Wang, Chunhua

AU - Weng, Bo

AU - Liao, Yuhe

AU - Liu, Biao

AU - Keshavarz, Masoumeh

AU - Ding, Yang

AU - Huang, Haowei

AU - Verhaeghe, Davy

AU - Steele, Julian A.

AU - Feng, Wenhui

AU - Su, Bao Lian

AU - Hofkens, Johan

AU - Roeffaers, Maarten B.J.

PY - 2022/8/25

Y1 - 2022/8/25

N2 - Cs3Bi2Br9 decorated with crystalline-amorphous Pd nanocubes as cocatalysts is reported to photocatalytically coproduce ca. 1400 μmol h−1 g−1 of H2 and benzaldehyde from the selective benzyl alcohol oxidation. This route offers an alternative for photocatalytic H2 generation using metal halide perovskites under mild conditions.

AB - Cs3Bi2Br9 decorated with crystalline-amorphous Pd nanocubes as cocatalysts is reported to photocatalytically coproduce ca. 1400 μmol h−1 g−1 of H2 and benzaldehyde from the selective benzyl alcohol oxidation. This route offers an alternative for photocatalytic H2 generation using metal halide perovskites under mild conditions.

UR - https://www.scopus.com/pages/publications/85138493679

U2 - 10.1039/d2cc02453e

DO - 10.1039/d2cc02453e

M3 - Article

C2 - 36065893

AN - SCOPUS:85138493679

SN - 1359-7345

VL - 58

SP - 10691

EP - 10694

JO - Chemical Communications

JF - Chemical Communications

IS - 76

ER -

Simultaneous photocatalytic H₂ generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs₃Bi₂Br₉

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Simultaneous photocatalytic H2 generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs3Bi2Br9

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Physical Chemistry and characterization(PC2)

Cite this

Simultaneous photocatalytic H₂ generation and organic synthesis over crystalline-amorphous Pd nanocube decorated Cs₃Bi₂Br₉