Self-collisional broadening and shift coefficients of lines in the v4+v5 band of C212H2 from 173.2 to 298.2K by diode-laser spectroscopy

M. Dhyne, P. Joubert, Claude Populaire, M. Lepère

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Abstract

The pressure-induced self-shift and broadening coefficients for seven lines of C212H2 in the v4+v5 band located around 1330cm have been measured using a tunable diode-laser spectrometer coupled with a low temperature absorption cell. The measurement of these coefficients was realized at five temperatures ranging from 173.2 to 273.2K (and also 298.2K for shift) in order to determine their temperature dependence. The broadening coefficients were obtained by fitting to the experimental profile the Voigt lineshape and the Rautian and the Galatry models which take into account the collisional narrowing due to molecular confinement (Dicke effect). The shift coefficients were determined using a procedure, where calibration lines were simultaneously recorded with transitions from the gas sample under study. The results have been compared with previous experimental data. Our coefficients of collisional broadening, γ0, as well as the temperature dependence parameters, n, are in satisfactory agreement with previous studies. The pressure broadening coefficients, γ0, are in good agreement with those reported for various vibrational bands, indicating that they are insensitive to vibrational excitation. The pressure shift coefficients, δ0, by contrast, are found to differ substantially among vibrational bands.
Original languageEnglish
Pages (from-to)969-979
Number of pages11
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume112
Issue number6
DOIs
Publication statusPublished - 1 Apr 2011

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Laser spectroscopy
laser spectroscopy
Semiconductor lasers
diodes
shift
coefficients
Temperature
Spectrometers
Gases
laser spectrometers
Calibration
pressure broadening
temperature dependence
profiles
cells
gases
excitation

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title = "Self-collisional broadening and shift coefficients of lines in the v4+v5 band of C212H2 from 173.2 to 298.2K by diode-laser spectroscopy",
abstract = "The pressure-induced self-shift and broadening coefficients for seven lines of C212H2 in the v4+v5 band located around 1330cm have been measured using a tunable diode-laser spectrometer coupled with a low temperature absorption cell. The measurement of these coefficients was realized at five temperatures ranging from 173.2 to 273.2K (and also 298.2K for shift) in order to determine their temperature dependence. The broadening coefficients were obtained by fitting to the experimental profile the Voigt lineshape and the Rautian and the Galatry models which take into account the collisional narrowing due to molecular confinement (Dicke effect). The shift coefficients were determined using a procedure, where calibration lines were simultaneously recorded with transitions from the gas sample under study. The results have been compared with previous experimental data. Our coefficients of collisional broadening, γ0, as well as the temperature dependence parameters, n, are in satisfactory agreement with previous studies. The pressure broadening coefficients, γ0, are in good agreement with those reported for various vibrational bands, indicating that they are insensitive to vibrational excitation. The pressure shift coefficients, δ0, by contrast, are found to differ substantially among vibrational bands.",
author = "M. Dhyne and P. Joubert and Claude Populaire and M. Lep{\`e}re",
note = "Copyright 2011 Elsevier B.V., All rights reserved.",
year = "2011",
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day = "1",
doi = "10.1016/j.jqsrt.2010.12.006",
language = "English",
volume = "112",
pages = "969--979",
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TY - JOUR

T1 - Self-collisional broadening and shift coefficients of lines in the v4+v5 band of C212H2 from 173.2 to 298.2K by diode-laser spectroscopy

AU - Dhyne, M.

AU - Joubert, P.

AU - Populaire, Claude

AU - Lepère, M.

N1 - Copyright 2011 Elsevier B.V., All rights reserved.

PY - 2011/4/1

Y1 - 2011/4/1

N2 - The pressure-induced self-shift and broadening coefficients for seven lines of C212H2 in the v4+v5 band located around 1330cm have been measured using a tunable diode-laser spectrometer coupled with a low temperature absorption cell. The measurement of these coefficients was realized at five temperatures ranging from 173.2 to 273.2K (and also 298.2K for shift) in order to determine their temperature dependence. The broadening coefficients were obtained by fitting to the experimental profile the Voigt lineshape and the Rautian and the Galatry models which take into account the collisional narrowing due to molecular confinement (Dicke effect). The shift coefficients were determined using a procedure, where calibration lines were simultaneously recorded with transitions from the gas sample under study. The results have been compared with previous experimental data. Our coefficients of collisional broadening, γ0, as well as the temperature dependence parameters, n, are in satisfactory agreement with previous studies. The pressure broadening coefficients, γ0, are in good agreement with those reported for various vibrational bands, indicating that they are insensitive to vibrational excitation. The pressure shift coefficients, δ0, by contrast, are found to differ substantially among vibrational bands.

AB - The pressure-induced self-shift and broadening coefficients for seven lines of C212H2 in the v4+v5 band located around 1330cm have been measured using a tunable diode-laser spectrometer coupled with a low temperature absorption cell. The measurement of these coefficients was realized at five temperatures ranging from 173.2 to 273.2K (and also 298.2K for shift) in order to determine their temperature dependence. The broadening coefficients were obtained by fitting to the experimental profile the Voigt lineshape and the Rautian and the Galatry models which take into account the collisional narrowing due to molecular confinement (Dicke effect). The shift coefficients were determined using a procedure, where calibration lines were simultaneously recorded with transitions from the gas sample under study. The results have been compared with previous experimental data. Our coefficients of collisional broadening, γ0, as well as the temperature dependence parameters, n, are in satisfactory agreement with previous studies. The pressure broadening coefficients, γ0, are in good agreement with those reported for various vibrational bands, indicating that they are insensitive to vibrational excitation. The pressure shift coefficients, δ0, by contrast, are found to differ substantially among vibrational bands.

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