Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

A. Krief; H.Y. Gondal; A. Kremer

doi:10.1039/b808695h

Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

A. Krief, H.Y. Gondal, A. Kremer

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(1S)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry using regiocontrolled epoxide ring opening, diol mono-oxidation and cyclopropanation. © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	4753-4755
Number of pages	3
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b808695h
Publication status	Published - 21 Oct 2008

Keywords

Cyclohexanols
Epoxy Compounds
Molecular Structure
Pyrethrins
Stereoisomerism

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10.1039/b808695h

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abstract = "(1S)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry using regiocontrolled epoxide ring opening, diol mono-oxidation and cyclopropanation. {\textcopyright} The Royal Society of Chemistry.",

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AU - Krief, A.

AU - Gondal, H.Y.

AU - Kremer, A.

PY - 2008/10/21

Y1 - 2008/10/21

N2 - (1S)-cis-Chrysanthemic acid has been prepared in a few steps with complete control of the relative and absolute stereochemistry using regiocontrolled epoxide ring opening, diol mono-oxidation and cyclopropanation. © The Royal Society of Chemistry.

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KW - Cyclohexanols

KW - Epoxy Compounds

KW - Molecular Structure

KW - Pyrethrins

KW - Stereoisomerism

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Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol

Abstract

Keywords

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