Sealing of porous low-k dielectrics: an ellipsometric porosimetry study of UV-O3 oxidized SiOxCy films

Caroline Whelan, Quoc Le, Francesca Cecchet, Alessandra Satta, Jean-Jacques Pireaux, Petra Rudolf, Karen Maex

Research output: Contribution to journalArticlepeer-review

Abstract

The ongoing evolution from to insulator materials with lower dielectric constant, k, through the introduction of pores, brings new challenges in terms of processing and reliability. Porosity enhances penetration of undesired chemical species. A method of sealing microporous low-k dielectric chemical vapor deposited silicon oxycarbide films using UV-ozone induced oxidation has been investigated. The film thickness, refractive index, porosity, pore size, and sealing as a function of exposure time have been characterized by ellipsometry. The films are sealed without modification of the underlying porosity, an essential first step in integrating porous materials. © 2003 The Electrochemical Society. All rights reserved.
Original languageEnglish
Pages (from-to)F8-F10
JournalElectrochemical and Solid State Letters
Volume7
Issue number2
DOIs
Publication statusPublished - 3 Dec 2003

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