TY - JOUR
T1 - Room temperature silylation of alcohols catalyzed by metal organic frameworks
AU - Dhakshinamoorthy, Amarajothi
AU - Santiago-Portillo, Andrea
AU - Concepción, Patricia
AU - Herance, José R.
AU - Navalón, Sergio
AU - Alvaro, Mercedes
AU - Garcia, Hermenegildo
N1 - Publisher Copyright:
© 2017 The Royal Society of Chemistry.
Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2017
Y1 - 2017
N2 - The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction conditions as evidenced by powder XRD and can be reused with minimal activity decrease.
AB - The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH)(BDC) is stable under the reaction conditions as evidenced by powder XRD and can be reused with minimal activity decrease.
UR - http://www.scopus.com/inward/record.url?scp=85024856555&partnerID=8YFLogxK
U2 - 10.1039/c7cy00834a
DO - 10.1039/c7cy00834a
M3 - Article
AN - SCOPUS:85024856555
SN - 2044-4753
VL - 7
SP - 2445
EP - 2449
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
IS - 12
ER -