Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Sayandip Chakraborty; Lei Hu; Nikolay Tumanov; Johan Wouters; Raphaël Robiette; Guillaume Berionni

doi:10.1039/d4cc01868k

Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Sayandip Chakraborty, Lei Hu, Nikolay Tumanov, Johan Wouters, Raphaël Robiette, Guillaume Berionni

Research output: Contribution to specialist publication › Article

22 Downloads (Pure)

Abstract

Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

Original language	English
Pages	7073-7076
Number of pages	4
Volume	60
No.	55
Specialist publication	Chemical Communications
DOIs	https://doi.org/10.1039/d4cc01868k
Publication status	Published - 18 Jun 2024

Access to Document

10.1039/d4cc01868k

d4cc01868kFinal published version, 983 KBLicence: CC BY

Cite this

@misc{72f54d8480b546dfb39aafa06f4465e7,

title = "Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines",

abstract = "Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.",

author = "Sayandip Chakraborty and Lei Hu and Nikolay Tumanov and Johan Wouters and Rapha{\"e}l Robiette and Guillaume Berionni",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

month = jun,

day = "18",

doi = "10.1039/d4cc01868k",

language = "English",

volume = "60",

pages = "7073--7076",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - GEN

T1 - Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

AU - Chakraborty, Sayandip

AU - Hu, Lei

AU - Tumanov, Nikolay

AU - Wouters, Johan

AU - Robiette, Raphaël

AU - Berionni, Guillaume

PY - 2024/6/18

Y1 - 2024/6/18

N2 - Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

AB - Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

UR - http://www.scopus.com/inward/record.url?scp=85198039888&partnerID=8YFLogxK

U2 - 10.1039/d4cc01868k

DO - 10.1039/d4cc01868k

M3 - Article

SN - 1359-7345

VL - 60

SP - 7073

EP - 7076

JO - Chemical Communications

JF - Chemical Communications

ER -

Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Abstract

Access to Document

Other files and links

Embargoed Document

Fingerprint

Geometrically constrained phosphines and fluorophosphonium ions for frustrated Lewis pairs catalysis

Cite this

Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Abstract

Access to Document

Other files and links

Embargoed Document

Fingerprint

Activities

Geometrically constrained phosphines and fluorophosphonium ions for frustrated Lewis pairs catalysis

Cite this