Regioselective 1-4 addition of acyl and equivalents to α-enones

J. Lucchetti, W. Dumont, A. Krief

Research output: Contribution to journalArticle

Abstract

2-lithio-1,3-dithianes, bis(phenylthio)alkyllithiums and bis(methylseleno)alkyllithiums add 1-4 to α-enones if HMPT is present in the medium prior to the addition of enones. Most of the reactions occur under kinetic control.
Original languageEnglish
Pages (from-to)2695-2696
Number of pages2
JournalTetrahedron Letters
Volume20
Issue number29
Publication statusPublished - 1 Jan 1979

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Kinetics
1,3-dithiane

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abstract = "2-lithio-1,3-dithianes, bis(phenylthio)alkyllithiums and bis(methylseleno)alkyllithiums add 1-4 to α-enones if HMPT is present in the medium prior to the addition of enones. Most of the reactions occur under kinetic control.",
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Regioselective 1-4 addition of acyl and equivalents to α-enones. / Lucchetti, J.; Dumont, W.; Krief, A.

In: Tetrahedron Letters, Vol. 20, No. 29, 01.01.1979, p. 2695-2696.

Research output: Contribution to journalArticle

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AU - Krief, A.

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AB - 2-lithio-1,3-dithianes, bis(phenylthio)alkyllithiums and bis(methylseleno)alkyllithiums add 1-4 to α-enones if HMPT is present in the medium prior to the addition of enones. Most of the reactions occur under kinetic control.

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