Reaction of 1,3-diselenanes with metal amides

A. Krief; L. Defrère

doi:10.1016/0040-4039(96)00356-5

Reaction of 1,3-diselenanes with metal amides

A. Krief, L. Defrère

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.

Original language	English
Pages (from-to)	2667-2670
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	15
DOIs	https://doi.org/10.1016/0040-4039(96)00356-5
Publication status	Published - 8 Apr 1996

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title = "Reaction of 1,3-diselenanes with metal amides",

abstract = "1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.",

author = "A. Krief and L. Defr{\`e}re",

year = "1996",

month = apr,

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doi = "10.1016/0040-4039(96)00356-5",

language = "English",

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T1 - Reaction of 1,3-diselenanes with metal amides

AU - Krief, A.

AU - Defrère, L.

PY - 1996/4/8

Y1 - 1996/4/8

N2 - 1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.

AB - 1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.

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U2 - 10.1016/0040-4039(96)00356-5

DO - 10.1016/0040-4039(96)00356-5

M3 - Article

AN - SCOPUS:19244385153

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VL - 37

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Reaction of 1,3-diselenanes with metal amides

Abstract

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