Projects per year
Abstract
Bending the planar trigonal boron center of triphenylborane by connecting its aryl rings with carbon or phosphorus linkers gave access to a series of 9-boratriptycene derivatives with unprecedented structures and reactivities. NMR spectroscopy and X-ray diffraction of the Lewis adducts of these non-planar boron Lewis acids with weak Lewis base revealed particularly strong covalent bond formation. The first Lewis adduct of a trivalent boron compounds with the Tf 2N − anion illustrates the unrivaled Lewis acidity of these species. Increasing the pyramidalization of the boron center and using a cationic phosphonium linker resulted in an exceptional enhancement of Lewis acidity. Introduction of a phosphorus and a boron atom at each edge of a triptycene framework, allowed access to new bifunctional Lewis acid-base 9-phospha-10-boratriptycenes featuring promising reactivity for the activation of carbon-halogen bonds.
Original language | English |
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Pages (from-to) | 16889-16893 |
Number of pages | 5 |
Journal | Angewandte Chemie. International edition |
Volume | 58 |
Issue number | 47 |
DOIs | |
Publication status | Published - 18 Nov 2019 |
Keywords
- boron
- Lewis acids
- Lewis superacid
- non-planar
- triarylboranes
Fingerprint
Dive into the research topics of 'Pushing the Lewis Acidity Boundaries of Boron Compounds With Non‐Planar Triarylboranes Derived from Triptycenes'. Together they form a unique fingerprint.Projects
- 2 Finished
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CÉCI – Consortium of high performance computing centers
CHAMPAGNE, B. (PI), Lazzaroni, R. (PI), Geuzaine , C. (CoI), Chatelain, P. (CoI) & Knaepen, B. (CoI)
1/01/18 → 31/12/22
Project: Research
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Density Functional Theory Study of 1,3-Dipolar Cycloadditions Reactions
Champagne, B. (PI) & Adjieufack, A. I. (PI)
1/11/17 → 31/12/20
Project: Research
Equipment
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High Performance Computing Technology Platform
Champagne, B. (Manager)
Technological Platform High Performance ComputingFacility/equipment: Technological Platform
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Physical Chemistry and characterization(PC2)
Wouters, J. (Manager), Aprile, C. (Manager) & Fusaro, L. (Manager)
Technological Platform Physical Chemistry and characterizationFacility/equipment: Technological Platform
Activities
- 1 Oral presentation
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Invited Lecture - University Paul Sabatier of Toulouse, France
Berionni, G. (Invited speaker)
18 Dec 2019Activity: Talk or presentation types › Oral presentation
Press/Media
Datasets
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CCDC 1908093: Experimental Crystal Structure Determination
Saida, A. B. (Contributor), Chardon, A. (Contributor), Osi, A. (Contributor), Tumanov, N. (Contributor), Wouters, J. (Contributor), Adjieufack, A. I. (Contributor), Champagne, B. (Contributor) & Berionni, G. (Contributor), University of Namur, 18 Nov 2019
DOI: 10.5517/ccdc.csd.cc221jd2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc221jd2&sid=DataCite
Dataset
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CCDC 1908094: Experimental Crystal Structure Determination
Saida, A. B. (Contributor), Chardon, A. (Contributor), Osi, A. (Contributor), Tumanov, N. (Contributor), Wouters, J. (Contributor), Adjieufack, A. I. (Contributor), Champagne, B. (Contributor) & Berionni, G. (Contributor), University of Namur, 18 Nov 2019
DOI: 10.5517/ccdc.csd.cc221jf3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc221jf3&sid=DataCite
Dataset
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CCDC 1938005: Experimental Crystal Structure Determination
Saida, A. B. (Contributor), Chardon, A. (Contributor), Osi, A. (Contributor), Tumanov, N. (Contributor), Wouters, J. (Contributor), Adjieufack, A. I. (Contributor), Champagne, B. (Contributor) & Berionni, G. (Contributor), University of Namur, 18 Nov 2019
DOI: 10.5517/ccdc.csd.cc231n94, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc231n94&sid=DataCite
Dataset