Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles

Jerzy Radecki; Iwona Stenka; Eduard Dolusic; Wim Dehaen; Janez Plavec

doi:10.2174/1386207043328724

Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles

Jerzy Radecki, Iwona Stenka, Eduard Dolusic, Wim Dehaen, Janez Plavec

Namur Research Institute for Life Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The results of studies on the use of corrole derivatives as a host ligand in the PVC liquid membrane electrodes and their ability for the potentiometric high-throughput discrimination of nitrophenol guests have been presented. The significance of parameters which govern the mechanism of generation of potentiometric signals such as the attachment of substituents in the corrole structure, acidity and lipophilicity of the guests, and pH of the aqueous solutions has been discussed in details. Supramolecular recognition processes between corroles and para-nitrophenol molecules have been confirmed by independent NMR measurements.

Original language	English
Pages (from-to)	375-381
Number of pages	7
Journal	Combinatorial Chemistry & High Throughput Screening
Volume	7
Issue number	4
DOIs	https://doi.org/10.2174/1386207043328724
Publication status	Published - 2004

Keywords

Neutral nitrophenols
Potentiometric discrimination
PVC-electrodes
Corroles

Access to Document

10.2174/1386207043328724

http://www.eurekaselect.com/61778/article/potentiometric-discrimination-neutral-forms-nitrophenol-isomers-liquid-membrane

21 Citations
5 Article
3 Poster

Determination of interaction strength between corrole and phenol derivatives in aqueous media using atomic force microscopy
Szymanska, I., Dolusic, E., Dehaen, W., Maes, W., Ito, T. & Radecka, H., 2009, In: Supramolecular Chemistry. 21, 7, p. 555-563 9 p.
Research output: Contribution to journal › Article › peer-review
Gold Electrode Incorporating Corrole as an Ion-Channel Mimetic Sensor for Determination of Dopamine
Kurzatkowska, K., Dolusic, E., Dehaen, W., Sieron-Stoltny, K., Sieron, A. & Radecka, H., 2009, In: Analytical Chemistry. 81, 17, p. 7397-7405 9 p.
Research output: Contribution to journal › Article › peer-review
Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes
Rohand, T., Dolusic, E., Ngo, T. H., Maes, W. & Dehaen, W., 2007, In: ARKIVOC. 2007, x, p. 307-324 18 p.
Research output: Contribution to journal › Article › peer-review

1 Participation in conference

XXVIII International Symposium on Macrocyclic Chemistry
Dolusic, E. (Poster)
13 Jul 2003 → 18 Jul 2003
Activity: Participating in or organising an event types › Participation in conference

PhD in organic chemistry Katholieke Universiteit Leuven, Belgium, 2000 - 2004 (Prof. Wim Dehaen)
Dolusic, E. (Author), 2004
Student thesis: Doc types › Doctor of Sciences

Cite this

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title = "Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles",

abstract = "The results of studies on the use of corrole derivatives as a host ligand in the PVC liquid membrane electrodes and their ability for the potentiometric high-throughput discrimination of nitrophenol guests have been presented. The significance of parameters which govern the mechanism of generation of potentiometric signals such as the attachment of substituents in the corrole structure, acidity and lipophilicity of the guests, and pH of the aqueous solutions has been discussed in details. Supramolecular recognition processes between corroles and para-nitrophenol molecules have been confirmed by independent NMR measurements.",

keywords = " Neutral nitrophenols, Potentiometric discrimination, PVC-electrodes, Corroles",

author = "Jerzy Radecki and Iwona Stenka and Eduard Dolusic and Wim Dehaen and Janez Plavec",

year = "2004",

doi = "10.2174/1386207043328724",

language = "English",

volume = "7",

pages = "375--381",

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T1 - Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles

AU - Radecki, Jerzy

AU - Stenka, Iwona

AU - Dolusic, Eduard

AU - Dehaen, Wim

AU - Plavec, Janez

PY - 2004

Y1 - 2004

N2 - The results of studies on the use of corrole derivatives as a host ligand in the PVC liquid membrane electrodes and their ability for the potentiometric high-throughput discrimination of nitrophenol guests have been presented. The significance of parameters which govern the mechanism of generation of potentiometric signals such as the attachment of substituents in the corrole structure, acidity and lipophilicity of the guests, and pH of the aqueous solutions has been discussed in details. Supramolecular recognition processes between corroles and para-nitrophenol molecules have been confirmed by independent NMR measurements.

AB - The results of studies on the use of corrole derivatives as a host ligand in the PVC liquid membrane electrodes and their ability for the potentiometric high-throughput discrimination of nitrophenol guests have been presented. The significance of parameters which govern the mechanism of generation of potentiometric signals such as the attachment of substituents in the corrole structure, acidity and lipophilicity of the guests, and pH of the aqueous solutions has been discussed in details. Supramolecular recognition processes between corroles and para-nitrophenol molecules have been confirmed by independent NMR measurements.

KW - Neutral nitrophenols

KW - Potentiometric discrimination

KW - PVC-electrodes

KW - Corroles

U2 - 10.2174/1386207043328724

DO - 10.2174/1386207043328724

M3 - Article

VL - 7

SP - 375

EP - 381

JO - Combinatorial Chemistry & High Throughput Screening

JF - Combinatorial Chemistry & High Throughput Screening

IS - 4

ER -

Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles

Abstract

Keywords

Access to Document

Fingerprint

Research output

Determination of interaction strength between corrole and phenol derivatives in aqueous media using atomic force microscopy

Gold Electrode Incorporating Corrole as an Ion-Channel Mimetic Sensor for Determination of Dopamine

Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes

Activities

XXVIII International Symposium on Macrocyclic Chemistry

Student theses

PhD in organic chemistry Katholieke Universiteit Leuven, Belgium, 2000 - 2004 (Prof. Wim Dehaen)

Cite this