Perpendicular bands of 1,3,5-triazine: the ν10/2ν14 dyad of 12C14N3H3, 12C15N3H3 and 13C14N3H3

W. Bodenmüller, M. Pfeffer, A. Ruoff, J. Schroderus, J. Walrand, G. Blanquet

Research output: Contribution to journalArticle

Abstract

The analysis of the high resolution FTIR spectra and the diode laser spectra of the ν(E′)/2ν(A′ ⊕ E′) dyad of CNH, CNH and CNH is reported. The components of this dyad are found to form a system coupled by Fermi, l(-1, 2)- and l(2, 2)-resonances causing an 'infinite chain'. A truncated model of dimensions 6 × 6 including a virtual level was chosen accounting well for all perturbations. All assigned lines belong to ν and 2ν, respectively. No transitions of 2ν were detected. Some lines of 2ν were observed. But they are so heavily blended that assignments cannot be given with certainty. The upper state constants, the resonance parameters and the constants ω, χ, and g were derived from the fit of 4554 lines (CNH), 6626 lines (CNH) and 4671 lines (CNH). The results are summarized in the Tables 1-3.
Original languageEnglish
Pages (from-to)69-79
Number of pages11
JournalJournal of molecular structure
Volume599
DOIs
Publication statusPublished - 12 Dec 2001

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@article{9bc81baaa0c740e18cbba957f0a0587a,
title = "Perpendicular bands of 1,3,5-triazine: the ν10/2ν14 dyad of 12C14N3H3, 12C15N3H3 and 13C14N3H3",
abstract = "The analysis of the high resolution FTIR spectra and the diode laser spectra of the ν(E′)/2ν(A′ ⊕ E′) dyad of CNH, CNH and CNH is reported. The components of this dyad are found to form a system coupled by Fermi, l(-1, 2)- and l(2, 2)-resonances causing an 'infinite chain'. A truncated model of dimensions 6 × 6 including a virtual level was chosen accounting well for all perturbations. All assigned lines belong to ν and 2ν, respectively. No transitions of 2ν were detected. Some lines of 2ν were observed. But they are so heavily blended that assignments cannot be given with certainty. The upper state constants, the resonance parameters and the constants ω, χ, and g were derived from the fit of 4554 lines (CNH), 6626 lines (CNH) and 4671 lines (CNH). The results are summarized in the Tables 1-3.",
author = "W. Bodenm{\"u}ller and M. Pfeffer and A. Ruoff and J. Schroderus and J. Walrand and G. Blanquet",
note = "Copyright 2008 Elsevier B.V., All rights reserved.",
year = "2001",
month = "12",
day = "12",
doi = "10.1016/S0022-2860(01)00845-6",
language = "English",
volume = "599",
pages = "69--79",
journal = "Journal of molecular structure",
issn = "0022-2860",
publisher = "Elsevier",

}

Perpendicular bands of 1,3,5-triazine: the ν10/2ν14 dyad of 12C14N3H3, 12C15N3H3 and 13C14N3H3. / Bodenmüller, W.; Pfeffer, M.; Ruoff, A.; Schroderus, J.; Walrand, J.; Blanquet, G.

In: Journal of molecular structure, Vol. 599, 12.12.2001, p. 69-79.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Perpendicular bands of 1,3,5-triazine: the ν10/2ν14 dyad of 12C14N3H3, 12C15N3H3 and 13C14N3H3

AU - Bodenmüller, W.

AU - Pfeffer, M.

AU - Ruoff, A.

AU - Schroderus, J.

AU - Walrand, J.

AU - Blanquet, G.

N1 - Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2001/12/12

Y1 - 2001/12/12

N2 - The analysis of the high resolution FTIR spectra and the diode laser spectra of the ν(E′)/2ν(A′ ⊕ E′) dyad of CNH, CNH and CNH is reported. The components of this dyad are found to form a system coupled by Fermi, l(-1, 2)- and l(2, 2)-resonances causing an 'infinite chain'. A truncated model of dimensions 6 × 6 including a virtual level was chosen accounting well for all perturbations. All assigned lines belong to ν and 2ν, respectively. No transitions of 2ν were detected. Some lines of 2ν were observed. But they are so heavily blended that assignments cannot be given with certainty. The upper state constants, the resonance parameters and the constants ω, χ, and g were derived from the fit of 4554 lines (CNH), 6626 lines (CNH) and 4671 lines (CNH). The results are summarized in the Tables 1-3.

AB - The analysis of the high resolution FTIR spectra and the diode laser spectra of the ν(E′)/2ν(A′ ⊕ E′) dyad of CNH, CNH and CNH is reported. The components of this dyad are found to form a system coupled by Fermi, l(-1, 2)- and l(2, 2)-resonances causing an 'infinite chain'. A truncated model of dimensions 6 × 6 including a virtual level was chosen accounting well for all perturbations. All assigned lines belong to ν and 2ν, respectively. No transitions of 2ν were detected. Some lines of 2ν were observed. But they are so heavily blended that assignments cannot be given with certainty. The upper state constants, the resonance parameters and the constants ω, χ, and g were derived from the fit of 4554 lines (CNH), 6626 lines (CNH) and 4671 lines (CNH). The results are summarized in the Tables 1-3.

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U2 - 10.1016/S0022-2860(01)00845-6

DO - 10.1016/S0022-2860(01)00845-6

M3 - Article

VL - 599

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EP - 79

JO - Journal of molecular structure

JF - Journal of molecular structure

SN - 0022-2860

ER -